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The\n                    <jats:italic>E\/Z<\/jats:italic>\n                    isomerization of a truxene\u2010based phosphaalkene, i.\u2009e. TruxC=P\u2010Mes* (Mes*=2,4,6\u2010tris\u2010\n                    <jats:italic>t<\/jats:italic>\n                    \u2010butyl\u2010benzene), is accomplished by irradiation, metal coordination, or deprotonation of the truxene core. 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