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Such C\u2212C bond formations generally proceed smoothly and selective. In contrast, nucleophilic addition at carbon monoxide is considerably more complex and unselective due to the instability of polar metal acyl intermediates. Herein, we report a magnesium alkyl complex, stabilised with a dipyrromethenide ligand, and its reactivity with CO<jats:sub>2<\/jats:sub> and CO. Whilst the reaction with CO<jats:sub>2<\/jats:sub> gave the expected carboxylate, reaction with CO took a surprising course, resulting in an alkoxide by formation of three new C\u2212C bonds in a single reaction. An intertwined experimental and computational approach sheds light on the unusual reactivity of a carbene intermediate.<\/jats:p>","DOI":"10.1002\/chem.202404028","type":"journal-article","created":{"date-parts":[[2024,11,7]],"date-time":"2024-11-07T10:49:42Z","timestamp":1730976582000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["A Rare Case of Magnesium Alkyl Mediated CO\u2010to\u2010Alkoxide Conversion"],"prefix":"10.1002","volume":"31","author":[{"given":"Oliver P. 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