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In this research, we report on zeolitic octahedral metal oxides based on cobalt vanadotungstates, which act as the catalysts for the oxidation of methane using molecular oxygen as the oxidant without co\u2010reductants at a low temperature of 90\u2009\u00b0C even as low as 60\u2009\u00b0C. This catalytic process results in the high\u2010yield production of methanol as the primary product. The micropores within the catalyst are critical for achieving high activity in the reaction, in which molecular oxygen is activated. The active species in the reaction are found to be hydroxyl\u2010based. Both VO<jats:sub>5<\/jats:sub> with reduced V<jats:sup>4+<\/jats:sup> and Co<jats:sup>2+<\/jats:sup> are crucial for generating the active species for the reaction.<\/jats:p>","DOI":"10.1002\/chem.202404037","type":"journal-article","created":{"date-parts":[[2025,1,7]],"date-time":"2025-01-07T22:46:40Z","timestamp":1736290000000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Low\u2010Temperature Oxidation of Methane to Methanol on a Zeolitic Octahedral Metal Oxide"],"prefix":"10.1002","volume":"31","author":[{"given":"Niu","family":"Guo","sequence":"first","affiliation":[{"name":"School of Materials Science and Chemical Engineering Ningbo University  Ningbo, Zhejiang 315211 P. R. 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