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Using the fluorinated\n                    <jats:sup>2F<\/jats:sup>\n                    ((DMP)\n                    <jats:sub>3<\/jats:sub>\n                    C\n                    <jats:sup>+<\/jats:sup>\n                    ) as a precursor, fluorinated tetramethoxy\u2010 and dimethoxyquin\u2010 acridinium salts (\n                    <jats:sup>\n                      <jats:bold>2F<\/jats:bold>\n                    <\/jats:sup>\n                    <jats:bold>4<\/jats:bold>\n                    and\n                    <jats:sup>\n                      <jats:bold>2F<\/jats:bold>\n                    <\/jats:sup>\n                    <jats:bold>5<\/jats:bold>\n                    respectively) and trioxo\u2010, azadioxo\u2010, and diazaoxo\u2010 triangulenium salts (\n                    <jats:sup>\n                      <jats:bold>2F<\/jats:bold>\n                    <\/jats:sup>\n                    <jats:bold>6<\/jats:bold>\n                    ,\n                    <jats:sup>\n                      <jats:bold>2F<\/jats:bold>\n                    <\/jats:sup>\n                    <jats:bold>7<\/jats:bold>\n                    and\n                    <jats:sup>\n                      <jats:bold>2F<\/jats:bold>\n                    <\/jats:sup>\n                    <jats:bold>8<\/jats:bold>\n                    respectively) were synthesized successfully in good to moderate yields. Fluorination induced significant red shifts in absorption (16 to 29\u2005nm) and emission (13 to 41\u2005nm) maxima, and increased electrophilicity as evidenced by lower reduction potentials. X\u2010ray structural analysis showed distinct packing patterns compared to the non\u2010fluorinated analogues, indicating the presence of molecular dipoles.\n                  <\/jats:p>","DOI":"10.1002\/chem.202404135","type":"journal-article","created":{"date-parts":[[2025,1,29]],"date-time":"2025-01-29T15:08:05Z","timestamp":1738163285000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Exploring the Synthesis and Properties of Fluorinated Cationic Triangulenes and Their Precursors"],"prefix":"10.1002","volume":"31","author":[{"given":"Ramandeep","family":"Kaur","sequence":"first","affiliation":[{"name":"Department of Chemistry and Biochemistry University of Arizona  Tucson AZ 85750 United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4390-4769","authenticated-orcid":false,"given":"Jules","family":"Moutet","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry University of Arizona  Tucson AZ 85750 United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"David D.","family":"Mills","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry University of Arizona  Tucson AZ 85750 United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3892-3893","authenticated-orcid":false,"given":"Thomas L.","family":"Gianetti","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry University of Arizona  Tucson AZ 85750 United States"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,2,11]]},"reference":[{"key":"e_1_2_9_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3cs60461f"},{"key":"e_1_2_9_2_1","unstructured":"\u00a0"},{"key":"e_1_2_9_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c10457"},{"key":"e_1_2_9_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.dyepig.2019.107866"},{"key":"e_1_2_9_5_2","first-page":"249","volume-title":"Methods in Enzymology","author":"Laursen B. 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