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Herein, we utilized a facile visible\u2010light\u2010assisted liquid\u2010phase method involving adjusting reaction time to generate active sites, successfully synthesizing one\u2010dimensional (1D) PdAg NAs rich in defects. The optimized 1D PdAg NA exhibits remarkable electrochemical activity, stability, and antipoisonous properties in glycerol oxidation reaction (GOR) and ethanol oxidation reaction (EOR), far exceeding pure Pd and commercial Pd\/C catalysts. Notably, compared to glycerol oxidation (1496\u2005mA\u2009mg<jats:sup>\u22121<\/jats:sup><jats:sub>Pd<\/jats:sub> and 4.13\u2005mA\u2009cm<jats:sup>\u22122<\/jats:sup>), the optimized PdAg NA demonstrated higher mass activity (2990\u2005mA\u2009mg<jats:sup>\u22121<\/jats:sup><jats:sub>Pd<\/jats:sub>) and specific activity (7.86\u2005mA\u2009cm<jats:sup>\u22122<\/jats:sup>) in ethanol oxidation. In summary, this work may provide a strategy for designing low\u2010cost electrocatalysts enriched with defects, thereby promoting the development of high\u2010performance alcohol oxidation reactions.<\/jats:p>","DOI":"10.1002\/chem.202404172","type":"journal-article","created":{"date-parts":[[2025,1,9]],"date-time":"2025-01-09T05:27:29Z","timestamp":1736400449000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["One\u2010dimensional Branched PdAg Nanoalloy Rich in Defects for Boosting Glycerol and Ethanol Oxidation"],"prefix":"10.1002","volume":"31","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-2855-186X","authenticated-orcid":false,"given":"De\u2010Xin","family":"Tan","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering Lingnan Normal University  524048 Zhanjiang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yan\u2010li","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Lingnan Normal University  524048 Zhanjiang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao\u2010Mei","family":"Ning","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Lingnan Normal University  524048 Zhanjiang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao\u2010Li","family":"Luo","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Lingnan Normal University  524048 Zhanjiang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chun\u2010Ru","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Lingnan Normal University  524048 Zhanjiang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiao","family":"Xiao","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Lingnan Normal University  524048 Zhanjiang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jian\u2010Hong","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Lingnan Normal University  524048 Zhanjiang China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,1,21]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2022.166112"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2009.11.145"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr9000995"},{"key":"e_1_2_8_4_1","first-page":"140","volume":"1","author":"Mares-Briones F.","year":"2024","journal-title":"Int. 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