{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T14:37:19Z","timestamp":1786977439681,"version":"build-2736575974"},"reference-count":73,"publisher":"Wiley","issue":"9","license":[{"start":{"date-parts":[[2025,1,5]],"date-time":"2025-01-05T00:00:00Z","timestamp":1736035200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["HA 3466\/11-1"],"award-info":[{"award-number":["HA 3466\/11-1"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2025,2,12]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Lewis acid\u2010base adducts between potassium dihydrogenpnictogenides [K(18c6)PnH\n                    <jats:sub>2<\/jats:sub>\n                    ] (Pn=P, As) and Trialkylgallanes (GaMe\n                    <jats:sub>3<\/jats:sub>\n                    , GaEt\n                    <jats:sub>3<\/jats:sub>\n                    , Ga\n                    <jats:italic>t<\/jats:italic>\n                    Bu\n                    <jats:sub>3<\/jats:sub>\n                    ) as well as BH\n                    <jats:sub>3<\/jats:sub>\n                    were synthesized. In the course of these investigations, we were able to fully characterize a row of compounds of the type [K(18c6)(thf)\n                    <jats:sub>0\u20102<\/jats:sub>\n                    ][PnH\n                    <jats:sub>2<\/jats:sub>\n                    (ER\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ] (E=B: R=H; E=Ga: R=Me, Et,\n                    <jats:italic>t<\/jats:italic>\n                    Bu). Based on the successful syntheses of these species, we also synthesized several compounds of the composition [K(18c6)(thf)\n                    <jats:sub>0\u20102<\/jats:sub>\n                    ][Pn(SiMe\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    (ER\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>n<\/jats:sub>\n                    ] (n=1, 2) starting from [KPn(SiMe\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ] (Pn=P and As) and ER\n                    <jats:sub>3<\/jats:sub>\n                    (E=B, Al, In: R=Me; E=Ga: R=Me, Et,\n                    <jats:italic>t<\/jats:italic>\n                    Bu). All isolated compounds, were examined by NMR spectroscopy, infra\u2010red spectroscopy and elemental analysis. A selection of the compounds presented were also examined by means of X\u2010ray structure analysis on the single crystal. The obtained adducts of negatively charged [PnH\n                    <jats:sub>2<\/jats:sub>\n                    ]\n                    <jats:sup>\u2212<\/jats:sup>\n                    and [Pn(SiMe\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ]\n                    <jats:sup>\u2212<\/jats:sup>\n                    fragments with Lewis acids are a class of compounds that has scarcely been investigated to date.\n                  <\/jats:p>","DOI":"10.1002\/chem.202404199","type":"journal-article","created":{"date-parts":[[2024,12,11]],"date-time":"2024-12-11T10:25:22Z","timestamp":1733912722000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Synthesis of Lewis Acid\u2010Base Adducts Between Potassium Dihydrogenpnictogenides and Group 13 Lewis Acids"],"prefix":"10.1002","volume":"31","author":[{"given":"Kevin","family":"Dollberg","sequence":"first","affiliation":[{"name":"Fachbereich Chemie Philipps-Universit\u00e4t Marburg  Hans-Meerwein-Stra\u00dfe 4 35043 Marburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nick","family":"Michel","sequence":"additional","affiliation":[{"name":"Fachbereich Chemie Philipps-Universit\u00e4t Marburg  Hans-Meerwein-Stra\u00dfe 4 35043 Marburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hanne","family":"Schm\u00fccker","sequence":"additional","affiliation":[{"name":"Fachbereich Chemie Philipps-Universit\u00e4t Marburg  Hans-Meerwein-Stra\u00dfe 4 35043 Marburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Stefan","family":"Seus","sequence":"additional","affiliation":[{"name":"Fachbereich Chemie Philipps-Universit\u00e4t Marburg  Hans-Meerwein-Stra\u00dfe 4 35043 Marburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Celina","family":"Jakobi","sequence":"additional","affiliation":[{"name":"Fachbereich Chemie Philipps-Universit\u00e4t Marburg  Hans-Meerwein-Stra\u00dfe 4 35043 Marburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Roman\u2010Malte","family":"Richter","sequence":"additional","affiliation":[{"name":"Fachbereich Chemie Philipps-Universit\u00e4t Marburg  Hans-Meerwein-Stra\u00dfe 4 35043 Marburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Carsten","family":"von H\u00e4nisch","sequence":"additional","affiliation":[{"name":"Fachbereich Chemie Philipps-Universit\u00e4t Marburg  Hans-Meerwein-Stra\u00dfe 4 35043 Marburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,1,5]]},"reference":[{"key":"e_1_2_8_1_1","first-page":"248","volume":"1","author":"Sturgill J. 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