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Investigations of the ternary system Zr\u2013V\u2212Al showed, in contrast to the system Hf\u2013V\u2212Al, that no superstructures can be observed within the solid solution Zr(V<jats:sub>1\u2013<jats:italic>x<\/jats:italic><\/jats:sub>Al<jats:sub><jats:italic>x<\/jats:italic><\/jats:sub>)<jats:sub>2<\/jats:sub>. High values of <jats:italic>x<\/jats:italic> form aluminum rich phases that adopt the hexagonal MgZn<jats:sub>2<\/jats:sub> type structure while low values of <jats:italic>x<\/jats:italic> lead to vanadium rich phases that adopt the cubic MgCu<jats:sub>2<\/jats:sub> type. All samples were investigated by powder X\u2010ray diffraction experiments. Single crystal studies indicated that no superstructure formation is present in the investigated samples. <jats:sup>27<\/jats:sup>Al MAS NMR investigations confirmed these findings. For ZrAl<jats:sub>2<\/jats:sub>, quantum\u2010chemical calculations helped with the analysis of the <jats:sup>27<\/jats:sup>Al NMR spectrum of the binary endmember of the solid solution. Some of the prepared samples were investigated with respect to their magnetic properties. The investigated compounds show Pauli\u2010paramagnetism, in Zr(V<jats:sub>0.875<\/jats:sub>Al<jats:sub>0.125<\/jats:sub>)<jats:sub>2<\/jats:sub> in addition superconductivity with a critical temperature of <jats:italic>T<\/jats:italic><jats:sub>C<\/jats:sub>=4.17(1)\u2005K was observed. Investigations of compositions that do not belong to the Laves phase regime clearly indicate that the MgZn<jats:sub>2<\/jats:sub> type structure is still the dominant phase. Regardless of the starting composition chosen, the hexagonal Laves phase was mostly present.<\/jats:p>","DOI":"10.1002\/chem.202404248","type":"journal-article","created":{"date-parts":[[2024,12,13]],"date-time":"2024-12-13T05:31:13Z","timestamp":1734067873000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Systematic Investigations of the Solid Solution Zr(V<sub>1\u2013<i>x<\/i><\/sub>Al<sub><i>x<\/i><\/sub>)<sub>2<\/sub> Adopting the Laves Phase Structures"],"prefix":"10.1002","volume":"31","author":[{"given":"Elias C. 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