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Both complexes show a distinct redox chemistry, which was first investigated by cyclic voltammetry. Subsequently, the monoanions [K(L)(sol)<jats:sub>n<\/jats:sub>][(Cp\u2019\u2019\u2019Co)<jats:sub>3<\/jats:sub>(\u03bc<jats:sub>3<\/jats:sub>,\u03b7<jats:sup>2<\/jats:sup>:\u03b7<jats:sup>2<\/jats:sup>:\u03b7<jats:sup>2<\/jats:sup>\u2010E<jats:sub>3<\/jats:sub>)(\u03bc<jats:sub>3<\/jats:sub>\u2010E)] (E=P, L=18cr6, sol=dme, n=2 (<jats:bold>5<\/jats:bold>), E=As, L=2,2,2\u2010crypt, n=0 (<jats:bold>6<\/jats:bold>)), the monocations [(Cp\u2019\u2019\u2019Co)<jats:sub>3<\/jats:sub>(\u03bc<jats:sub>3<\/jats:sub>,\u03b7<jats:sup>2<\/jats:sup>:\u03b7<jats:sup>2<\/jats:sup>:\u03b7<jats:sup>2<\/jats:sup>\u2010E<jats:sub>3<\/jats:sub>)(\u03bc<jats:sub>3<\/jats:sub>\u2010E)][FAl] (E=P (<jats:bold>7<\/jats:bold>), As (<jats:bold>8<\/jats:bold>)) and the dications [(Cp\u2019\u2019\u2019Co)<jats:sub>3<\/jats:sub>(\u03bc<jats:sub>3<\/jats:sub>,\u03b7<jats:sup>3<\/jats:sup>:\u03b7<jats:sup>3<\/jats:sup>:\u03b7<jats:sup>3<\/jats:sup>\u2010E<jats:sub>4<\/jats:sub>)][TEF]<jats:sub>2<\/jats:sub> (E=P (<jats:bold>9<\/jats:bold>), As (<jats:bold>10<\/jats:bold>)) could be realized experimentally and isolated in moderate to good yields. All compounds were characterized by single crystal X\u2010ray structure analysis, NMR and EPR spectroscopy, mass spectrometry and elemental analysis.<\/jats:p>","DOI":"10.1002\/chem.202404361","type":"journal-article","created":{"date-parts":[[2025,1,8]],"date-time":"2025-01-08T11:19:06Z","timestamp":1736335146000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis and Redox Chemistry of Co<sub>3<\/sub>E<sub>4<\/sub> (E=P, As) Clusters"],"prefix":"10.1002","volume":"31","author":[{"given":"Martin","family":"Piesch","sequence":"first","affiliation":[{"name":"Institute of Inorganic Chemistry University of Regensburg  93040 Regensburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sabrina B.","family":"Dinauer","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Regensburg  93040 Regensburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0009-0003-3590-9919","authenticated-orcid":false,"given":"Christoph","family":"Riesinger","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Regensburg  93040 Regensburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"G\u00e1bor","family":"Bal\u00e1zs","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Regensburg  93040 Regensburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2182-5020","authenticated-orcid":false,"given":"Manfred","family":"Scheer","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Regensburg  93040 Regensburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2025,1,16]]},"reference":[{"key":"e_1_2_8_1_1","unstructured":"\u00a0"},{"key":"e_1_2_8_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr500208k"},{"key":"e_1_2_8_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b10960"},{"key":"e_1_2_8_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201410301"},{"key":"e_1_2_8_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201404665"},{"key":"e_1_2_8_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201502368"},{"key":"e_1_2_8_7_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CC09675E"},{"key":"e_1_2_8_8_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1227813"},{"key":"e_1_2_8_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja906695h"},{"key":"e_1_2_8_10_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1202"},{"key":"e_1_2_8_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b07430"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC09354K"},{"key":"e_1_2_8_13_1","unstructured":"\u00a0"},{"key":"e_1_2_8_14_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(92)80030-2"},{"key":"e_1_2_8_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19961290112"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3765(19981002)4:10<1910::AID-CHEM1910>3.0.CO;2-E"},{"key":"e_1_2_8_17_1","unstructured":"\u00a0"},{"key":"e_1_2_8_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.19960020217"},{"key":"e_1_2_8_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.19970030917"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.202200102"},{"key":"e_1_2_8_21_1","unstructured":"\u00a0"},{"key":"e_1_2_8_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201001000"},{"key":"e_1_2_8_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201610967"},{"key":"e_1_2_8_24_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4SC03543G"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201905240"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4DT01160K"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201916622"},{"key":"e_1_2_8_28_1","unstructured":"\u00a0"},{"key":"e_1_2_8_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar00105a003"},{"key":"e_1_2_8_30_2","doi-asserted-by":"crossref","unstructured":"K. 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