{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,22]],"date-time":"2026-07-22T01:02:38Z","timestamp":1784682158723,"version":"3.55.0"},"reference-count":61,"publisher":"Wiley","issue":"16","license":[{"start":{"date-parts":[[2025,1,28]],"date-time":"2025-01-28T00:00:00Z","timestamp":1738022400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2025,1,28]],"date-time":"2025-01-28T00:00:00Z","timestamp":1738022400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100018818","name":"National Research, Development and Innovation Office","doi-asserted-by":"publisher","award":["OTKA-FK-145841"],"award-info":[{"award-number":["OTKA-FK-145841"]}],"id":[{"id":"10.13039\/501100018818","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2025,3,17]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>New hybrids were synthesised by linking carboranes and siloles, both of which are known as aggregation\u2010induced emission active units. Although most of the newly synthesised systems do not display notable quantum yield either in solution or in the aggregated state, they emit strongly in the solid\u2010state, and a quantum yield of up to 100\u2009% can be achieved. The tailorable quantum yield can be attributed to the packing of the molecules in the crystal lattice ruled by the carborane and phenyl moieties according to the SC\u2010XRD data. Our experimental results, complemented by density functional theory calculations, show that the silole moiety primarily influences the photophysical properties. At the same time, the carborane serves as a steric building block without direct responsibility for the aggregation\u2010induced emission property. The patterns of substituents can alter the absorption and emission properties.<\/jats:p>","DOI":"10.1002\/chem.202404462","type":"journal-article","created":{"date-parts":[[2025,1,20]],"date-time":"2025-01-20T06:24:26Z","timestamp":1737354266000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Carborane\u2010Decorated Siloles with Highly Efficient Solid\u2010State Emissions \u2013 What Drives the Photophysical Properties?"],"prefix":"10.1002","volume":"31","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6122-2489","authenticated-orcid":false,"given":"Bal\u00e1zs","family":"Szathm\u00e1ri","sequence":"first","affiliation":[{"name":"Department of Inorganic and Analytical Chemistry Budapest University of Technology and Economics  M\u0171egyetem rkp.\u20053 H-1111 Budapest Hungary"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3033-2762","authenticated-orcid":false,"given":"D\u00f3ra","family":"Hessz","sequence":"additional","affiliation":[{"name":"Department of Physical Chemistry and Materials Science and MTA-BME Lend\u00fclet Quantum Chemistry Research Group Budapest University of Technology and Economics  M\u0171egyetem rkp.\u20053 H-1111 Budapest Hungary"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7671-039X","authenticated-orcid":false,"given":"D\u00e1niel","family":"Z\u00e1mb\u00f3","sequence":"additional","affiliation":[{"name":"Institute of Technical Physics and Materials Science HUN-REN Centre for Energy Research  Konkoly-Thege Mikl\u00f3s \u00fat 29\u201333 H-1121 Budapest Hungary"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Clemens","family":"Bruhn","sequence":"additional","affiliation":[{"name":"Institute of Chemistry and CINSat University of Kassel  Heinrich-Plett-Stra\u00dfe\u200540 34132 Kassel Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0551-3633","authenticated-orcid":false,"given":"Rudolf","family":"Pietschnig","sequence":"additional","affiliation":[{"name":"Institute of Chemistry and CINSat University of Kassel  Heinrich-Plett-Stra\u00dfe\u200540 34132 Kassel Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6320-8322","authenticated-orcid":false,"given":"Antal","family":"Udvardy","sequence":"additional","affiliation":[{"name":"Department of Physical Chemistry University of Debrecen  Egyetem t\u00e9r\u20051 H-4032 Debrecen Hungary"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2260-4641","authenticated-orcid":false,"given":"P\u00e1l","family":"Szab\u00f3","sequence":"additional","affiliation":[{"name":"Centre for Structural Science HUN-REN Research Centre for Natural Sciences  Magyar tud\u00f3sok k\u00f6r\u00fatja\u20052 H-1117 Budapest Hungary"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2727-7037","authenticated-orcid":false,"given":"Tam\u00e1s","family":"Holczbauer","sequence":"additional","affiliation":[{"name":"Chemical Crystallography Research Laboratory and Stereochemistry Research Group Institute for Organic Chemistry HUN-REN Research Centre for Natural Sciences  Magyar Tud\u00f3sok k\u00f6r\u00fatja\u20052\u2005A H-1117 Budapest Hungary"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Marcell J.","family":"Balogh","sequence":"additional","affiliation":[{"name":"Department of Inorganic and Analytical Chemistry Budapest University of Technology and Economics  M\u0171egyetem rkp.\u20053 H-1111 Budapest Hungary"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4787-9804","authenticated-orcid":false,"given":"Zsolt","family":"Kelemen","sequence":"additional","affiliation":[{"name":"Department of Inorganic and Analytical Chemistry Budapest University of Technology and Economics  M\u0171egyetem rkp.\u20053 H-1111 Budapest Hungary"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,1,28]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1cs15113d"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00263"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3BM00043E"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/b105159h"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7TC02511D"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/sstr.202300157"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3TC03278G"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202302767"},{"key":"e_1_2_8_9_1","author":"Chorbacher J.","year":"2024","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00198"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/pj.2017.56"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7TC03319B"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8TC03741H"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9BM00903E"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0QI00127A"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CC07211K"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201307333"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201402396"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC07093K"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0DT03618H"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201100046"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc38817k"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo401232a"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/srep04635"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4TA00397G"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo500884z"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo402884a"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201308486"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201901305"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2SC03511A"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-31267-7"},{"key":"e_1_2_8_32_1","doi-asserted-by":"crossref","unstructured":"D. Buzs\u00e1ki D. G\u00e1l Z. Harcsa-Pint\u00e9r L. Kalabay Z. Kelemen Chem. Eur. J.2024 30 e202402970.","DOI":"10.1002\/chem.202402970"},{"key":"e_1_2_8_33_1","author":"Buzs\u00e1ki D.","year":"2025","journal-title":"Inorg. Chem. Front."},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1515\/mgmc-2020-0015"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/om970091h"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(90)80153-Q"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1515\/pac-2014-1006"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1139\/v05-081"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules180910568"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1080\/10426507.2014.905574"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/0470857250"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1039\/CC9960002285"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201304321"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201304474"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201404743"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.2c02435"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201500002"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201916666"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2022.214779"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202101298"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.3c00019"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5SC01946J"},{"key":"e_1_2_8_53_1","unstructured":"M.\u2005J. Frisch G.\u2005W. Trucks H.\u2005B. Schlegel G.\u2005E. Scuseria M.\u2005A. Robb J.\u2005R. Cheeseman G. Scalmani V. Barone G.\u2005A. Petersson H. Nakatsuji X. Li M. Caricato A.\u2005V. Marenich J. Bloino B.\u2005G. Janesko R. Gomperts B. Mennucci H.\u2005P. Hratchian J.\u2005V. Ortiz A.\u2005F. Izmaylov J.\u2005L. Sonnenberg D. Williams-Young F. Ding F. Lipparini F. Egidi J. Goings B. Peng A. Petrone T. Henderson D. Ranasinghe V.\u2005G. Zakrzewski J. Gao N. Rega G. Zheng W. Liang M. Hada M. Ehara K. Toyota R. Fukuda J. Hasegawa M. Ishida T. Nakajima Y. Honda O. Kitao H. Nakai T. Vreven K. Throssell J.\u2005A. Montgomery\u2005Jr. J.\u2005E. Peralta F. Ogliaro M.\u2005J. Bearpark J.\u2005J. Heyd E.\u2005N. Brothers K.\u2005N. Kudin V.\u2005N. Staroverov T.\u2005A. Keith R. Kobayashi J. Normand K. Raghavachari A.\u2005P. Rendell J.\u2005C. Burant S.\u2005S. Iyengar J. Tomasi M. Cossi J.\u2005M. Millam M. Klene C. Adamo R. Cammi J.\u2005W. Ochterski R.\u2005L. Martin K. Morokuma O. Farkas J.\u2005B. Foresman D.\u2005J. Fox Gaussian 16 (Revision C.01) Gaussian Inc. Wallingford CT2016."},{"key":"e_1_2_8_54_1","volume-title":"IQmol (2.15.3.)","author":"Gilbert T. B.","year":"2021"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.20823"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1107\/S1600576721002910"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1107\/S2053273314026370"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1107\/S1600576719014092"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1107\/S2053229614024218"},{"key":"e_1_2_8_60_1","first-page":"1","volume":"76","author":"Spek A. L.","year":"2020","journal-title":"Acta Crystallogr."},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1107\/S1600576719014092"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202404462","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.202404462","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202404462","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,22]],"date-time":"2026-07-22T00:25:10Z","timestamp":1784679910000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.202404462"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,1,28]]},"references-count":61,"journal-issue":{"issue":"16","published-print":{"date-parts":[[2025,3,17]]}},"alternative-id":["10.1002\/chem.202404462"],"URL":"https:\/\/doi.org\/10.1002\/chem.202404462","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,1,28]]},"assertion":[{"value":"2024-12-03","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-01-28","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202404462"}}