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Especially the packing of the cages in the solid state has a significant effect on the porosity. Therefore, it is important to be able to control the packing pattern either by crystallization conditions or the interaction of molecular units, defined as crystal engineering synthons. Here, tribromoarene subunits as such are incorporated into cage structures, namely a [2+3] and a [4+4] imine cage, to study the reliability of this subunit as crystal engineering synthon. Several solvatomorphs of both cages were studied by single\u2010crystal X\u2010ray diffraction and packing patterns thoroughly analyzed. Among those solvatomorphs an interpenetrated Faujasite\u2010type supramolecular arrangement is found.<\/jats:p>","DOI":"10.1002\/chem.202404548","type":"journal-article","created":{"date-parts":[[2025,2,6]],"date-time":"2025-02-06T02:39:01Z","timestamp":1738809541000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Supramolecular Interpenetrated Faujasite\u2010Like Crystals from [4+4] Imine Cages"],"prefix":"10.1002","volume":"31","author":[{"given":"Jochen C.","family":"Lauer","sequence":"first","affiliation":[{"name":"Organisch-Chemisches Institut Ruprecht-Karls-Universit\u00e4t Heidelberg, Im Neuenheimer Feld 272  69120 Heidelberg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wen\u2010Shan","family":"Zhang","sequence":"additional","affiliation":[{"name":"Organisch-Chemisches Institut Ruprecht-Karls-Universit\u00e4t Heidelberg, Im Neuenheimer Feld 272  69120 Heidelberg 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