{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,21]],"date-time":"2026-06-21T06:27:55Z","timestamp":1782023275469,"version":"3.54.5"},"reference-count":50,"publisher":"Wiley","issue":"25","license":[{"start":{"date-parts":[[2025,4,7]],"date-time":"2025-04-07T00:00:00Z","timestamp":1743984000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2025,4,7]],"date-time":"2025-04-07T00:00:00Z","timestamp":1743984000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2025,5]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    New TiNiSi\u2010type compounds\n                    <jats:italic>A<\/jats:italic>\n                    LiAu (\n                    <jats:italic>A =<\/jats:italic>\n                    Ca, Sr, Ba, Eu, Yb) were obtained in the form of mm\u2010sized single crystals by high\u2010temperature centrifugation\u2010aided filtration from lithium melt. They are the first examples of TiNiSi\u2010type representatives containing Li and a transition metal. The metallic phases show paramagnetic (Ca) or diamagnetic (Sr, Ba, Yb) behavior or antiferromagnetic ordering below 19 K (Eu). A new structural description is based on a hexagonal close packing with\n                    <jats:italic>A<\/jats:italic>\n                    occupying all octahedral and Li occupying half of the tetrahedral voids in an ordered fashion. Chemical bonding analysis supports the structural description and reveals the formation of eight\u2010atomic\n                    <jats:italic>stella\u2013quadrangula<\/jats:italic>\n                    bonds pinned on the empty tetrahedral holes, a bonding picture known from elemental metals.\n                  <\/jats:p>","DOI":"10.1002\/chem.202500134","type":"journal-article","created":{"date-parts":[[2025,3,25]],"date-time":"2025-03-25T20:50:03Z","timestamp":1742935803000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["TiNiSi\u2010Type\n                    <i>A<\/i>\n                    LiAu (\n                    <i>A<\/i>\n                    = Ca, Sr, Ba, Eu, Yb) Compounds: Alternative Use of \u201cExcess\u201d Electrons"],"prefix":"10.1002","volume":"31","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5248-222X","authenticated-orcid":false,"given":"Peter","family":"H\u00f6hn","sequence":"first","affiliation":[{"name":"Max\u2010Planck\u2010Institut f\u00fcr Chemische Physik fester Stoffe Chemische Metallkunde  N\u00f6thnitzer Str. 40 Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0727-7702","authenticated-orcid":false,"given":"Daniel","family":"Men\u00e9ndez Crespo","sequence":"additional","affiliation":[{"name":"Max\u2010Planck\u2010Institut f\u00fcr Chemische Physik fester Stoffe Chemische Metallkunde  N\u00f6thnitzer Str. 40 Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0748-981X","authenticated-orcid":false,"given":"Matej","family":"Bobnar","sequence":"additional","affiliation":[{"name":"Max\u2010Planck\u2010Institut f\u00fcr Chemische Physik fester Stoffe Chemische Metallkunde  N\u00f6thnitzer Str. 40 Dresden Germany"},{"name":"Department of Condensed Matter Physics Jo\u017eef Stefan Institute  Jamova cesta 39 Ljubljana Slovenia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9837-7516","authenticated-orcid":false,"given":"Primo\u017e","family":"Ko\u017eelj","sequence":"additional","affiliation":[{"name":"Max\u2010Planck\u2010Institut f\u00fcr Chemische Physik fester Stoffe Chemische Metallkunde  N\u00f6thnitzer Str. 40 Dresden Germany"},{"name":"Department of Condensed Matter Physics Jo\u017eef Stefan Institute  Jamova cesta 39 Ljubljana Slovenia"},{"name":"Department of Physics, Faculty of Mathematics and Physics University of Ljubljana  Ljubljana Slovenia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8580-2381","authenticated-orcid":false,"given":"Mitja","family":"Krnel","sequence":"additional","affiliation":[{"name":"Max\u2010Planck\u2010Institut f\u00fcr Chemische Physik fester Stoffe Chemische Metallkunde  N\u00f6thnitzer Str. 40 Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7418-9892","authenticated-orcid":false,"given":"Yurii","family":"Prots","sequence":"additional","affiliation":[{"name":"Max\u2010Planck\u2010Institut f\u00fcr Chemische Physik fester Stoffe Chemische Metallkunde  N\u00f6thnitzer Str. 40 Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Marcus","family":"Schmidt","sequence":"additional","affiliation":[{"name":"Max\u2010Planck\u2010Institut f\u00fcr Chemische Physik fester Stoffe Chemische Metallkunde  N\u00f6thnitzer Str. 40 Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2382-2261","authenticated-orcid":false,"given":"Frank R.","family":"Wagner","sequence":"additional","affiliation":[{"name":"Max\u2010Planck\u2010Institut f\u00fcr Chemische Physik fester Stoffe Chemische Metallkunde  N\u00f6thnitzer Str. 40 Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3891-9584","authenticated-orcid":false,"given":"Yuri","family":"Grin","sequence":"additional","affiliation":[{"name":"Max\u2010Planck\u2010Institut f\u00fcr Chemische Physik fester Stoffe Chemische Metallkunde  N\u00f6thnitzer Str. 40 Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,4,7]]},"reference":[{"key":"e_1_2_7_1_1","volume-title":"Pearson's Crystal Data: Crystal Structure Database for Inorganic Compounds","author":"Villars P.","year":"2023"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0567740868003432"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1524\/zkri.216.3.127.20327"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3DT00621B"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic401166v"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4DT02220C"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1524\/zpch.1987.154.Part_1_2.201"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/0925-8388(93)90435-P"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19613100304"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022-4596(78)90099-3"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19936190621"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022-5088(69)90160-X"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.202300059"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3749(200011)626:11<2257::AID-ZAAC2257>3.0.CO;2-#"},{"key":"e_1_2_7_15_1","first-page":"53","volume-title":"Handbook on the Physics and Chemistry of Rare Earths","author":"Fisk Z.","year":"1989"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0925-8388(00)01259-7"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.3390\/inorganics4040042"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/0925-8388(92)90185-C"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0567739476001551"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022-5088(82)90209-0"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0365110X65002189"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic980223e"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022-5088(79)90223-6"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1524\/zkri.1971.133.133.127"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/0925-8388(96)80030-2"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202014284"},{"key":"e_1_2_7_27_1","volume-title":"FHI\u2010aims, an all electron, numerically tabulated, atom\u2010centred\u2010orbital electronic structure code, 071914_7","author":"MS1P e.V","year":"2024"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cpc.2009.06.022"},{"key":"e_1_2_7_29_1","volume-title":"Atoms in Molecules \u2013 A Quantum Theory","author":"Bader R. F. W.","year":"1994"},{"key":"e_1_2_7_30_1","author":"Wagner F. R.","year":"2025","journal-title":"Acta Crystallogr. A"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp992784c"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp054727r"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.20985"},{"key":"e_1_2_7_34_1","doi-asserted-by":"crossref","first-page":"345","DOI":"10.1002\/9783527664696.ch10","volume-title":"The Chemical Bond","author":"Grin Y.","year":"2014"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/open.202200118"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199718081"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja107436n"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.progsolidstchem.2008.07.001"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.progsolidstchem.2010.08.003"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201501236"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1515\/ijmr-1968-590512"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1515\/zpch-1936-3327"},{"key":"e_1_2_7_43_1","unstructured":"STOE&C.GmbH WinXPow Darmstadt Germany 2003."},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0108767307043930"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1107\/S2053229614024218"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/andp.19103371006"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/andp.19123420404"},{"key":"e_1_2_7_48_1","first-page":"222","volume-title":"Comprehensive Inorganic Chemistry III (Third Edition)","author":"Wagner F. R.","year":"2023"},{"key":"e_1_2_7_49_1","unstructured":"M.Kohout DGRID4.6\u20105.0 Dresden Germany 2018\u20132021."},{"key":"e_1_2_7_50_1","volume-title":"QTgeom","author":"Wagner F. R.","year":"2021"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202500134","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.202500134","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202500134","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,1,28]],"date-time":"2026-01-28T08:49:06Z","timestamp":1769590146000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.202500134"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,4,7]]},"references-count":50,"journal-issue":{"issue":"25","published-print":{"date-parts":[[2025,5]]}},"alternative-id":["10.1002\/chem.202500134"],"URL":"https:\/\/doi.org\/10.1002\/chem.202500134","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,4,7]]},"assertion":[{"value":"2025-01-13","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-03-24","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-04-07","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202500134"}}