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The\n                    <jats:bold>V\u2013Cu\u2010MOF<\/jats:bold>\n                    demonstrates exceptional performance in the selective oxidation of 2,3,6\u2010trimethylphenol to 2,3,5\u2010trimethyl\u20101,4\u2010benzoquinone within just 10 minutes under mild conditions using hydrogen peroxide as the oxidant. The\n                    <jats:bold>V\u2013Cu\u2010MOF<\/jats:bold>\n                    exhibits remarkable versatility, efficiently oxidizing various substituted phenols while maintaining high catalytic activity. Additionally, it shows excellent recyclability, with conversion and selectivity consistently exceeding 97\u2009% after multiple cycles. Mechanistic studies reveal that the reaction benefits from dual\u2010active centers {V\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>6<\/jats:sub>\n                    }\n                    <jats:sup>2\u2212<\/jats:sup>\n                    clusters and binuclear copper units. The weak substrate adsorption by binuclear copper prevents catalyst poisoning, ensuring sustained activity throughout the process.\n                  <\/jats:p>","DOI":"10.1002\/chem.202500255","type":"journal-article","created":{"date-parts":[[2025,2,12]],"date-time":"2025-02-12T04:25:21Z","timestamp":1739334321000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["A Stable Polyoxovanadate\u2010based Metal\u2212organic Framework Containing Dual Catalytic Sites for Efficient Synthesis of\n                    <i>p\u2013<\/i>\n                    benzoquinones"],"prefix":"10.1002","volume":"31","author":[{"given":"Tian\u2010Yi","family":"Dang","sequence":"first","affiliation":[{"name":"Key Laboratory of Polyoxometalate and Reticular Material Chemistry of the Ministry of Education College of Chemistry Northeast Normal University  Changchun Jilin 130024 P. R. China"},{"name":"School of Chemistry South China Normal University  Guangzhou Guangdong 510006 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hong\u2010Rui","family":"Tian","sequence":"additional","affiliation":[{"name":"Key Laboratory of Polyoxometalate and Reticular Material Chemistry of the Ministry of Education College of Chemistry Northeast Normal University  Changchun Jilin 130024 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ying","family":"Lu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Polyoxometalate and Reticular Material Chemistry of the Ministry of Education College of Chemistry Northeast Normal University  Changchun Jilin 130024 P. R. 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