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Herein, we employ a ligand\u2010protected direct hydrogen reduction strategy to encapsulate ultrafine Pt clusters within hydrophobic silicalite\u20101 zeolite. C\n                    <jats:sub>s<\/jats:sub>\n                    \u2010corrected scanning transmission electron microscopy, x\u2010ray absorption, and solid nuclear magnetic resonance measurements confirmed that the Pt clusters are stabilized within zeolite channels by adjacent silanol groups. The optimized Pt@S\u20101\u2010400H catalyst achieved complete HCHO removal at room temperature, with even low Pt loading of 0.1 wt%, affording a high specific activity of 171.9 mol\n                    <jats:sub>HCHO<\/jats:sub>\n                    \u00b7mol\n                    <jats:sub>Pt<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00b7h\n                    <jats:sup>\u22121<\/jats:sup>\n                    , representing the top level among all state\u2010of\u2010the\u2010art Pt\u2010based catalysts. Significantly, the hydrophobic nature of silicalite\u20101 ensures excellent water resistance and long\u2010term stability for the Pt@S\u20101\u2010400H catalyst. In situ infrared spectroscopy reveals that silanol sites facilitate HCHO adsorption and the formation of formate intermediates. The synergistic effect between Pt clusters and adjacent silanol sites enhances the HCHO oxidation performance. The simple and cost\u2010effective approach, combined with its excellent activity and stability, holds significant potential for effectively eliminating indoor pollutants in practical applications.\n                  <\/jats:p>","DOI":"10.1002\/chem.202500405","type":"journal-article","created":{"date-parts":[[2025,3,28]],"date-time":"2025-03-28T01:16:20Z","timestamp":1743124580000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Integration of Ultrasmall Pt Clusters With Silanol Groups in Pure Silica Zeolites for Robust Formaldehyde Oxidation"],"prefix":"10.1002","volume":"31","author":[{"given":"Yue","family":"Sun","sequence":"first","affiliation":[{"name":"College of Chemistry and Chemical Engineering Key Laboratory of Shandong Provincial Universities for Functional Molecules and Materials Qingdao University  Qingdao Shandong 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