{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,27]],"date-time":"2026-06-27T08:43:52Z","timestamp":1782549832228,"version":"3.54.5"},"reference-count":50,"publisher":"Wiley","issue":"21","license":[{"start":{"date-parts":[[2025,3,12]],"date-time":"2025-03-12T00:00:00Z","timestamp":1741737600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/100007633","name":"Stiftelsen f\u00f6r Milj\u00f6strategisk Forskning","doi-asserted-by":"publisher","award":["SSF, EM16-0067)"],"award-info":[{"award-number":["SSF, EM16-0067)"]}],"id":[{"id":"10.13039\/100007633","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004063","name":"Knut och Alice Wallenbergs Stiftelse","doi-asserted-by":"publisher","award":["KAW, 2018.0074"],"award-info":[{"award-number":["KAW, 2018.0074"]}],"id":[{"id":"10.13039\/501100004063","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004359","name":"Vetenskapsr\u00e5det","doi-asserted-by":"publisher","award":["VR, 2020-05058"],"award-info":[{"award-number":["VR, 2020-05058"]}],"id":[{"id":"10.13039\/501100004359","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004359","name":"Vetenskapsr\u00e5det","doi-asserted-by":"publisher","award":["VR, 2020-03207"],"award-info":[{"award-number":["VR, 2020-03207"]}],"id":[{"id":"10.13039\/501100004359","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004527","name":"Energimyndigheten","doi-asserted-by":"publisher","award":["P48747-1"],"award-info":[{"award-number":["P48747-1"]}],"id":[{"id":"10.13039\/501100004527","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100016874","name":"Liam M. Kinne Foundation","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100016874","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100021590","name":"Sten K Johnsons stiftelse","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100021590","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2025,4,9]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>An Fe(III)\u2010NHC complex has been employed for the green light driven catalysis of base\u2010promoted homolytic aromatic substitution (BHAS) reactions. Tributylamine was used as a sacrificial electron donor, together with potassium carbonate as base in dimethyl sulfoxide as solvent. In contrast to previously studied photocatalysts, the excited Fe(III)\u2010NHC complex is not reducing the arylhalide substrates. Instead, the latter are activated by \u03b1\u2010aminoalkyl radicals formed upon reductive quenching of the photocatalyst by tributylamine. Avoiding strongly reducing photocatalysts as well as strong base, these mild reaction conditions allowed for the expansion of the substrate scope to accommodate also aldehyde and ester substituents. 100\u2009% conversion was obtained after 48\u2005h of irradiation. In this way a wide variety of cyclized products and their corresponding hydrodehalogenated products were obtained as isolated and pure compounds, in the vast majority of cases.<\/jats:p>","DOI":"10.1002\/chem.202500409","type":"journal-article","created":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T07:43:59Z","timestamp":1740123839000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Base\u2010Promoted Homolytic Aromatic Substitution (BHAS) Reactions and Hydrodehalogenations Driven by Green Light and an Iron(III)\u2010NHC Photoredox Catalyst"],"prefix":"10.1002","volume":"31","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6148-2259","authenticated-orcid":false,"given":"Lisa H. M.","family":"de Groot","sequence":"first","affiliation":[{"name":"Centre for Analysis and Synthesis (CAS) Department of Chemistry Lund University  SE-22100 Lund Sweden"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3388-1281","authenticated-orcid":false,"given":"Clara","family":"Garc\u00eda\u2010Mateos","sequence":"additional","affiliation":[{"name":"Centre for Analysis and Synthesis (CAS) Department of Chemistry Lund University  SE-22100 Lund Sweden"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9975-6577","authenticated-orcid":false,"given":"Catherine E.","family":"Johnson","sequence":"additional","affiliation":[{"name":"Department of Chemistry \u2013 \u00c5ngstr\u00f6m Laboratory Uppsala University  SE-75120 Uppsala Sweden"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0002-2972-5155","authenticated-orcid":false,"given":"Valt\u00fdr","family":"Freyr Hlynsson","sequence":"additional","affiliation":[{"name":"Centre for Analysis and Synthesis (CAS) Department of Chemistry Lund University  SE-22100 Lund Sweden"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5950-4818","authenticated-orcid":false,"given":"Alpesh K.","family":"Sharma","sequence":"additional","affiliation":[{"name":"Centre for Analysis and Synthesis (CAS) Department of Chemistry Lund University  SE-22100 Lund Sweden"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2246-1863","authenticated-orcid":false,"given":"Reiner","family":"Lomoth","sequence":"additional","affiliation":[{"name":"Department of Chemistry \u2013 \u00c5ngstr\u00f6m Laboratory Uppsala University  SE-75120 Uppsala Sweden"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9022-3165","authenticated-orcid":false,"given":"Kenneth","family":"W\u00e4rnmark","sequence":"additional","affiliation":[{"name":"Centre for Analysis and Synthesis (CAS) Department of Chemistry Lund University  SE-22100 Lund Sweden"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,3,12]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/9781118754887.ch9"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201101597"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja103050x"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja1080822"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b03442"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.862"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/ol8019764"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/asia.201301371"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/cs5011037"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr300503r"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/ol500614q"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/ol3034687"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1OB01673C"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b07373"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c07617"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-023-01297-9"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c01000"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2023.215522"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr500075s"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2OB00209D"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.5b00068"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CY01771C"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1452"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1258232"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC04677G"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja991365q"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0SC04387G"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aau7160"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/j100408a032"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp026743j"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.1c00558"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aba2419"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c06081"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.2c01779"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2SC02122F"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4SC02612H"},{"issue":"16","key":"e_1_2_8_37_1","first-page":"11299","volume":"146","author":"Wellauer J.","year":"2024","journal-title":"J. Am. Chem. Soc."},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c14248"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201804566"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature21430"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/pola.28098"},{"key":"e_1_2_8_42_1","unstructured":"J. Rumble T. J. Bruno M. J. Doa CRC Handbook of Chemistry and Physics 104th ed. CRC Press Taylor & Francis Group 2023."},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1139\/v94-004"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201602254"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2013.06.072"},{"key":"e_1_2_8_46_1","first-page":"714","volume":"27","author":"Roth H. G.","year":"2016","journal-title":"Synlett"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1038\/srep16397"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2pp05333k"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(99)00407-7"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS00358A"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202500409","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T13:00:08Z","timestamp":1760274008000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.202500409"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,3,12]]},"references-count":50,"journal-issue":{"issue":"21","published-print":{"date-parts":[[2025,4,9]]}},"alternative-id":["10.1002\/chem.202500409"],"URL":"https:\/\/doi.org\/10.1002\/chem.202500409","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,3,12]]},"assertion":[{"value":"2025-02-04","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-03-12","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202500409"}}