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However, achieving the red room\u2010temperature phosphorescence (RTP) from single benzene is still challenging. Utilizing the p\u2010\u03c0 conjugation, herein, we report a single benzene\u2010based push\u2010pull system with red RTP under ambient condition. One of the phosphors shows maximum RTP peak at 585\u00a0nm, along with shoulder peaks at 545\u00a0nm, 635\u00a0nm, and 700\u00a0nm. 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