{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,12]],"date-time":"2026-10-12T18:45:21Z","timestamp":1791830721318,"version":"4.3.4"},"reference-count":100,"publisher":"Wiley","issue":"33","license":[{"start":{"date-parts":[[2025,5,8]],"date-time":"2025-05-08T00:00:00Z","timestamp":1746662400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22001223"],"award-info":[{"award-number":["22001223"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001692","name":"Croucher Foundation","doi-asserted-by":"publisher","award":["2021"],"award-info":[{"award-number":["2021"]}],"id":[{"id":"10.13039\/501100001692","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2025,6,12]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Indigo, an ancient natural dye, featured excellent biodegradability to advance in sustainable polymer. Indigo amphiphiles can pave a way for sustainable supramolecular polymers in aqueous media for potential biomedical functional materials. However, contemporary indigo amphiphiles supramolecular commonly assemble into low aspect ratio nanostructures, which hampers the macroscopic soft scaffolds fabrications and smart functional material applications. In this study, we report a novel peripheral designed indigo bola\u2010amphiphiles (IBAs), which assemble into high aspect ratio supramolecular nanofibers in aqueous media. By employing a shear\u2010flow assembly technique with bio\u2010abundant calcium ions, IBAs assemble across multiple length scales into supramolecular macroscopic scaffolds. The structural characterizations of IBAs macroscopic soft scaffolds show different supramolecular structural packing information by scanning electron microscope and X\u2010ray scattering\/diffraction techniques. Our supramolecular nanoarchitectonic approach indicates the feasibility of using IBAs molecular design to construct supramolecular macroscopic materials with higher structural order for the future smart biofunctional materials and sustainable supramolecular polymer under more environmentally friendly conditions.<\/jats:p>","DOI":"10.1002\/chem.202500791","type":"journal-article","created":{"date-parts":[[2025,4,29]],"date-time":"2025-04-29T08:25:39Z","timestamp":1745915139000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Peripheral Designed Indigo Bola\u2010Amphiphiles for Supramolecular Assembled Nanoarchitectonics in Aqueous Media"],"prefix":"10.1002","volume":"31","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-5959-0613","authenticated-orcid":false,"given":"Leong\u2010Hung","family":"Cheung","sequence":"first","affiliation":[{"name":"The Hong Kong Polytechnic University Shenzhen Research Institute  Shenzhen 518057 China"},{"name":"Department of Applied Biology and Chemical Technology Research Institute for Future Food The Hong Kong Polytechnic University  Hong Kong China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Franco King\u2010Chi","family":"Leung","sequence":"additional","affiliation":[{"name":"The Hong Kong Polytechnic University Shenzhen Research Institute  Shenzhen 518057 China"},{"name":"Department of Applied Biology and Chemical Technology Research Institute for Future Food The Hong Kong Polytechnic University  Hong Kong China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,5,8]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1098\/rstb.2008.0304"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.1700782"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abg5433"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature21001"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.progpolymsci.2019.101197"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s43586-022-00124-8"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41598-024-59439-z"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-021-04350-0"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacsau.3c00544"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41578-020-0190-4"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41578-021-00363-3"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr990125q"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.progpolymsci.2022.101635"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1205962"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr900181u"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9PY01342C"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/453171a"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr500633b"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1038\/natrevmats.2016.24"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/cplu.202300694"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0TA11251H"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202301762"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200602815"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00369"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202007693"},{"key":"e_1_2_8_26_1","first-page":"267","volume-title":"Supramol. Assem. Based Electrost. Interact","year":"2022"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cis.2023.102892"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1017\/S0033583500001797"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/jss.400080404"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3CS00480E"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00630F"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/adom.201900033"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201906036"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201905966"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS00547A"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202204413"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2887"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b10778"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201905445"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c12318"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c03153"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CC02177F"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c01063"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/marc.202400261"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41428-023-00792-7"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202407130"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2022.08.034"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.dyepig.2022.110807"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.3762\/bjoc.20.142"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.3c16795"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/marc.202200438"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.dyepig.2024.112334"},{"key":"e_1_2_8_53_1","volume-title":"Ullmann's Encycl. Ind. Chem","author":"Paul R.","year":"2021"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.dyepig.2020.108570"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1186\/s40643-023-00626-7"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.biotechadv.2024.108374"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201102619"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4TC00550C"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.0c00601"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.dyepig.2020.108966"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.dyepig.2020.108749"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.dyepig.2021.110017"},{"key":"e_1_2_8_63_1","doi-asserted-by":"publisher","DOI":"10.1007\/s13762-023-04810-2"},{"key":"e_1_2_8_64_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b08726"},{"key":"e_1_2_8_65_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b07531"},{"key":"e_1_2_8_66_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.7b00638"},{"key":"e_1_2_8_67_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-44128-8"},{"key":"e_1_2_8_68_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-39944-x"},{"key":"e_1_2_8_69_1","author":"Gernet A.","year":"2024","journal-title":"ChemPhotoChem"},{"key":"e_1_2_8_70_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.dyepig.2020.108197"},{"key":"e_1_2_8_71_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.202100781"},{"key":"e_1_2_8_72_1","doi-asserted-by":"publisher","DOI":"10.1002\/cptc.202200004"},{"key":"e_1_2_8_73_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202200496"},{"key":"e_1_2_8_74_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2SC06790K"},{"key":"e_1_2_8_75_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c03543"},{"key":"e_1_2_8_76_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.colsurfa.2023.130939"},{"key":"e_1_2_8_77_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7SC04340F"},{"key":"e_1_2_8_78_1","doi-asserted-by":"publisher","DOI":"10.3390\/60900736"},{"key":"e_1_2_8_79_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202300981"},{"key":"e_1_2_8_80_1","doi-asserted-by":"publisher","DOI":"10.3762\/bjoc.20.23"},{"key":"e_1_2_8_81_1","doi-asserted-by":"publisher","DOI":"10.1039\/b925049m"},{"key":"e_1_2_8_82_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5NJ01594D"},{"key":"e_1_2_8_83_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.188201502274"},{"key":"e_1_2_8_84_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5MH00012B"},{"key":"e_1_2_8_85_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6QM00240D"},{"key":"e_1_2_8_86_1","doi-asserted-by":"publisher","DOI":"10.1016\/B978-0-12-816200-2.00001-3"},{"key":"e_1_2_8_87_1","doi-asserted-by":"publisher","DOI":"10.1093\/bulcsj\/uoad001"},{"key":"e_1_2_8_88_1","doi-asserted-by":"publisher","DOI":"10.1002\/cphc.202400596"},{"key":"e_1_2_8_89_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201106299"},{"key":"e_1_2_8_90_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo3021665"},{"key":"e_1_2_8_91_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar050199q"},{"key":"e_1_2_8_92_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(02)00740-2"},{"key":"e_1_2_8_93_1","doi-asserted-by":"publisher","DOI":"10.1002\/cptc.201700228"},{"key":"e_1_2_8_94_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2022.05.025"},{"key":"e_1_2_8_95_1","doi-asserted-by":"publisher","DOI":"10.1038\/nnano.2011.120"},{"key":"e_1_2_8_96_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b11318"},{"key":"e_1_2_8_97_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat2778"},{"key":"e_1_2_8_98_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200390319"},{"key":"e_1_2_8_99_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cplett.2004.07.115"},{"key":"e_1_2_8_100_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2004.04.037"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202500791","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T08:45:47Z","timestamp":1760258747000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.202500791"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,5,8]]},"references-count":100,"journal-issue":{"issue":"33","published-print":{"date-parts":[[2025,6,12]]}},"alternative-id":["10.1002\/chem.202500791"],"URL":"https:\/\/doi.org\/10.1002\/chem.202500791","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,5,8]]},"assertion":[{"value":"2025-02-28","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-04-29","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-05-08","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202500791"}}