{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T21:38:07Z","timestamp":1791236287664,"version":"4.1.0"},"reference-count":54,"publisher":"Wiley","issue":"30","license":[{"start":{"date-parts":[[2025,4,26]],"date-time":"2025-04-26T00:00:00Z","timestamp":1745625600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001691","name":"Japan Society for the Promotion of Science","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001691","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2025,5,27]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Cyanoborate anions are versatile bridging ligands that lead to structurally diverse compounds from a crystal engineering perspective. Herein, we report the synthesis of a cubane\u2010type tetranuclear Ru complex, [Ru\n                    <jats:sub>4<\/jats:sub>\n                    (Cp)\n                    <jats:sub>4<\/jats:sub>\n                    {B(CN)\n                    <jats:sub>4<\/jats:sub>\n                    }\n                    <jats:sub>4<\/jats:sub>\n                    ] (\n                    <jats:bold>1<\/jats:bold>\n                    , Cp = C\n                    <jats:sub>5<\/jats:sub>\n                    H\n                    <jats:sub>5<\/jats:sub>\n                    ),\u00a0obtained by photoirradiation of [Ru(Cp)(C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>6<\/jats:sub>\n                    )]B(CN)\n                    <jats:sub>4<\/jats:sub>\n                    in solution or by the reaction of [CpRu(MeCN)\n                    <jats:sub>3<\/jats:sub>\n                    ]\n                    <jats:sup>+<\/jats:sup>\n                    with KB(CN)\n                    <jats:sub>4<\/jats:sub>\n                    . This complex served as a host for various solvents, generating different pseudopolymorphs, including\n                    <jats:bold>\n                      1\u00b7\n                      <jats:italic>n<\/jats:italic>\n                      CH\n                      <jats:sub>2<\/jats:sub>\n                      Cl\n                      <jats:sub>2<\/jats:sub>\n                    <\/jats:bold>\n                    (\n                    <jats:italic>n<\/jats:italic>\n                    = 1, 2, 3),\n                    <jats:bold>\n                      1\u00b70.5C\n                      <jats:sub>6<\/jats:sub>\n                      H\n                      <jats:sub>6<\/jats:sub>\n                    <\/jats:bold>\n                    ,\n                    <jats:bold>\n                      1\u00b7C\n                      <jats:sub>6<\/jats:sub>\n                      H\n                      <jats:sub>5<\/jats:sub>\n                      Me\n                    <\/jats:bold>\n                    , and\n                    <jats:bold>1\u00b73THF<\/jats:bold>\n                    upon recrystallization. Moreover, the four free cyano groups in\n                    <jats:bold>1<\/jats:bold>\n                    allow it to act as a bridging ligand, facilitating the formation of 1D and 2D coordination polymers through reactions with transition metal complexes.\n                  <\/jats:p>","DOI":"10.1002\/chem.202500976","type":"journal-article","created":{"date-parts":[[2025,4,10]],"date-time":"2025-04-10T04:48:56Z","timestamp":1744260536000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Crystal Engineering of Cyanoborate\u2010Bridged Cubane\u2010Type Tetranuclear Ru Complex: Synthesis, Pseudopolymorphism, and Coordination Polymer Formation"],"prefix":"10.1002","volume":"31","author":[{"given":"Takumi","family":"Tominaga","sequence":"first","affiliation":[{"name":"Department of Chemistry Graduate School of Science Kobe University  Rokkodai, Nada Kobe Hyogo 657\u20138501 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0002-5573-5920","authenticated-orcid":false,"given":"Ryota","family":"Inoue","sequence":"additional","affiliation":[{"name":"Department of Chemistry Graduate School of Science Kobe University  Rokkodai, Nada Kobe Hyogo 657\u20138501 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6617-2994","authenticated-orcid":false,"given":"Ryo","family":"Sumitani","sequence":"additional","affiliation":[{"name":"Department of Chemistry Graduate School of Science Kobe University  Rokkodai, Nada Kobe Hyogo 657\u20138501 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5827-4237","authenticated-orcid":false,"given":"Ken'ichi","family":"Aoki","sequence":"additional","affiliation":[{"name":"Department of Chemistry Faculty of Science Division II Tokyo University of Science  1\u20133 Kagurazaka, Shinjuku\u2010ku Tokyo 162\u20138601 Japan"},{"name":"Department of Chemistry Graduate School of Science Tokyo University of Science  1\u20133 Kagurazaka, Shinjuku\u2010ku Tokyo 162\u20138601 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3446-2145","authenticated-orcid":false,"given":"Tomoyuki","family":"Mochida","sequence":"additional","affiliation":[{"name":"Department of Chemistry Graduate School of Science Kobe University  Rokkodai, Nada Kobe Hyogo 657\u20138501 Japan"},{"name":"Research Center for Membrane and Film Technology Kobe University  Rokkodai, Nada Kobe Hyogo 657\u20138501 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