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While current upcycling methods are typically successful in converting single\u2010component plastic waste, conversion of mixed plastics resembling real\u2010world plastic waste with a single catalytic system remains a challenge. In this manuscript, we report an upcycling method suitable for a range of polyolefins (including mixtures of PP, LDPE, HDPE, and PVC, the four most produced plastics), which selectively produces toluene, ethylbenzene, cumene, and propylbenzene in the presence of benzene. The generation of ethylbenzene and cumene as major upcycling products, currently produced from ethylene or propylene and benzene, effectively circumvents the thermodynamically unfavorable depolymerization of polyolefins, allowing polyolefins to function as olefin surrogates in organic transformations. The utilization of inexpensive AlCl\n                    <jats:sub>3<\/jats:sub>\n                    as a pre\u2010catalyst, tolerance to additives, and mild reaction conditions render this method readily adapted by the current industry setup. Therefore, this upcycling method may have some significant impact on the mitigation of the waste plastic crisis.\n                  <\/jats:p>","DOI":"10.1002\/chem.202501096","type":"journal-article","created":{"date-parts":[[2025,8,14]],"date-time":"2025-08-14T12:01:01Z","timestamp":1755172861000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Friedel\u2010Crafts Reaction with Polyolefins as Alkylation Reagents and Poly(vinyl chloride) as Initiator"],"prefix":"10.1002","volume":"31","author":[{"given":"Xinyue","family":"Tan","sequence":"first","affiliation":[{"name":"Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry Fudan University  Songhu Road 2005 Shanghai 200438 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yizhou","family":"Yang","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Molecular Catalysis and 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