{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,11]],"date-time":"2026-10-11T14:11:49Z","timestamp":1791727909158,"version":"4.3.4"},"reference-count":74,"publisher":"Wiley","issue":"36","license":[{"start":{"date-parts":[[2025,5,29]],"date-time":"2025-05-29T00:00:00Z","timestamp":1748476800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22278370"],"award-info":[{"award-number":["22278370"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2025,6,26]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Sulfonamides represent an important structural motif present in numerous drugs, however, the scarcity of synthetic methods for bicyclo[1.1.1]pentanesulfonamides has limited the applicability of this compound class. Herein, we report an energy transfer (EnT) promoted photocatalytic strategy for the synthesis of bicyclo[1.1.1]pentanesulfonamides via sulfonamidation of [1.1.1]propellane. This approach utilizes\n                    <jats:italic>N<\/jats:italic>\n                    \u2010nitrososulfonamides as precursors, facilitating the generation of sulfonamide radicals through homolytic cleavage under EnT promotion. These radicals were then found to engage in an addition reaction with [1.1.1]propellane, generating bicyclo[1.1.1]pentane (BCP) radicals that undergo subsequent C\u2500H, C\u2500X, C\u2500S, or C\u2500C coupling reactions to afford a variety of C3\u2010substituted bicyclo[1.1.1]pentanesulfonamides. This strategy featured mild conditions, operational simplicity, with high atomic utilization, and therefore not only offers an efficient synthesis of a range of C3\u2010versatile\u2010substituted BCP sulfonamides, but also significantly broadens the potential applicability of BCP\u2010sulfonamides in drug discovery.\n                  <\/jats:p>","DOI":"10.1002\/chem.202501164","type":"journal-article","created":{"date-parts":[[2025,5,30]],"date-time":"2025-05-30T00:30:08Z","timestamp":1748565008000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Visible Light\u2010Induced Sulfonamidation of [1.1.1]Propellane Promoted by Energy Transfer Catalysis"],"prefix":"10.1002","volume":"31","author":[{"given":"Deyou","family":"Lan","sequence":"first","affiliation":[{"name":"College of Pharmaceutical Sciences Zhejiang University of Technology  Hangzhou 310014 P. R. 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