{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,15]],"date-time":"2026-09-15T12:15:47Z","timestamp":1789474547008,"version":"build-2803163510"},"reference-count":48,"publisher":"Wiley","issue":"36","license":[{"start":{"date-parts":[[2025,5,27]],"date-time":"2025-05-27T00:00:00Z","timestamp":1748304000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2025,6,26]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    This study presents novel bispidine\u2010based Cu(II) coordination polymers (CPs) with remarkable dynamic properties, volatile organic compounds (VOCs) exchange, and selective adsorption capabilities. The coordination requirements of Cu(II) enable, as demonstrated by SC\u2010XRD and Powder X\u2010ray diffraction (P\u2010XRD), the formation of either 1D ribbon\u2010like (\n                    <jats:bold>\n                      1\u2010TCM\n                      <jats:sup>SC<\/jats:sup>\n                    <\/jats:bold>\n                    and\n                    <jats:bold>\n                      1\u2010H\n                      <jats:sub>2<\/jats:sub>\n                      O\n                      <jats:sup>SC<\/jats:sup>\n                    <\/jats:bold>\n                    ) or 2D (\n                    <jats:bold>\n                      1\u2010MeCN\n                      <jats:sup>SC<\/jats:sup>\n                    <\/jats:bold>\n                    ) extended frameworks depending on the ability of the trapped solvents to interact as hydrogen bond (HB) donor with the metal's counterion. Hirshfeld Surface (HS) analysis and in situ VT SC\u2010 and P\u2010XRD experiments reveal different interchain interactions in 1D\n                    <jats:italic>vs<\/jats:italic>\n                    2D CPs. Solvent exchange experiments on both single crystals (SCs) and microcrystalline samples, set up to evaluate differences in the CPs\u2019 dynamic nature, confirm the drastic effect of CP dimensionality. Additionally, an amorphous desolvated phase\n                    <jats:bold>\n                      1\u2010Amorph\n                      <jats:sup>Pwd<\/jats:sup>\n                    <\/jats:bold>\n                    was tested for VOC adsorption and demonstrated to display affinity for acetonitrile and nitromethane, with high selectivity for the latter, but also to have the ability to trap aromatic VOCs, capturing up to ca. 2\u00a0mmol\/g of solvent. The adsorption experiments, conducted at\n                    <jats:italic>r<\/jats:italic>\n                    .\n                    <jats:italic>t<\/jats:italic>\n                    ., 1 atm, and no prior activation, underscore the potential of these materials for environmental and industrial applications. This work emphasizes the unique dynamic and selective behavior of bispidine\u2010based CPs and provides a foundation for their scalability and practical implementation in VOCs capture technologies.\n                  <\/jats:p>","DOI":"10.1002\/chem.202501431","type":"journal-article","created":{"date-parts":[[2025,5,13]],"date-time":"2025-05-13T08:10:49Z","timestamp":1747123849000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Bispidine\u2010Based Copper(II) Coordination Polymers with Remarkable Dynamic Properties, Selective Volatile Organic Compounds Adsorption, and Exchange Capabilities"],"prefix":"10.1002","volume":"31","author":[{"given":"Meriem","family":"Goudjil","sequence":"first","affiliation":[{"name":"Department of Industrial Engineering University of Florence  via Santa Marta 3 50139 Firenze Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Martina","family":"Lippi","sequence":"additional","affiliation":[{"name":"Department of Industrial Engineering University of Florence  via Santa Marta 3 50139 Firenze Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chiara","family":"Pelosi","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Industrial Chemistry University of Pisa  via G. Moruzzi 13 56124 Pisa Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Luca","family":"Bernazzani","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Industrial Chemistry University of Pisa  via G. Moruzzi 13 56124 Pisa Italy"},{"name":"Institute for the Chemistry of Organometallic Compounds\u2010ICCOM Italian National Research Council\u2010CNR  via G. Moruzzi 13 56124 Pisa Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Patrizia","family":"Rossi","sequence":"additional","affiliation":[{"name":"Department of Industrial Engineering University of Florence  via Santa Marta 3 50139 Firenze Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Paola","family":"Paoli","sequence":"additional","affiliation":[{"name":"Department of Industrial Engineering University of Florence  via Santa Marta 3 50139 Firenze Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9280-3155","authenticated-orcid":false,"given":"Massimo","family":"Cametti","sequence":"additional","affiliation":[{"name":"Department of Chemistry Materials and Chemical Engineering \u201cGiulio Natta\u201d Politecnico di Milano  via Luigi Mancinelli 7 20131 Milano Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,5,27]]},"reference":[{"key":"e_1_2_9_1_1","volume-title":"The Chemistry of metal\u2010organic frameworks, 2 volume set: synthesis, characterization, and applications","author":"Kaskel S","year":"2016"},{"key":"e_1_2_9_1_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1230444"},{"key":"e_1_2_9_1_3","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2020.213295"},{"key":"e_1_2_9_1_4","doi-asserted-by":"publisher","DOI":"10.1021\/ja067374y"},{"key":"e_1_2_9_1_5","doi-asserted-by":"publisher","DOI":"10.1021\/ja502765n"},{"key":"e_1_2_9_1_6","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202304773"},{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS01160F"},{"key":"e_1_2_9_2_2","author":"Giakoumakis N. 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