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Higher oxidation states, that is, +II and\u00a0+III, are significantly less represented and predominantly adopt a square planar (\n                    <jats:italic>SP<\/jats:italic>\n                    \u20104) geometry around the metal center. In particular, well\u2010defined d\n                    <jats:sup>8<\/jats:sup>\n                    Ag\n                    <jats:sup>III<\/jats:sup>\n                    compounds are scarce, and include only a handful of examples exhibiting\n                    <jats:italic>out\u2010of\u2010plane<\/jats:italic>\n                    silver coordination. This\n                    <jats:italic>Concept Article<\/jats:italic>\n                    summarizes the strategies known to stabilize Ag\n                    <jats:sup>III<\/jats:sup>\n                    , as well as the unusual electronic structures (inverted ligand field) often found in these compounds. The intriguing case study of the expansion in the coordination number in Ag\n                    <jats:sup>III<\/jats:sup>\n                    CF\n                    <jats:sub>3<\/jats:sub>\n                    compounds will be highlighted.\n                  <\/jats:p>","DOI":"10.1002\/chem.202501606","type":"journal-article","created":{"date-parts":[[2025,7,21]],"date-time":"2025-07-21T07:15:01Z","timestamp":1753082101000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Platform Design Enabling Silver(III) Stabilization \u2500 The Uprise of Ag\n                    <sup>III<\/sup>\n                    CF\n                    <sub>3<\/sub>\n                    Chemistry?"],"prefix":"10.1002","volume":"31","author":[{"given":"Luca","family":"Demonti","sequence":"first","affiliation":[{"name":"Laboratoire H\u00e9t\u00e9rochimie Fondamentale et Appliqu\u00e9e (LHFA) Universit\u00e9 de Toulouse  CNRS. 118 Route de Narbonne Toulouse 31062 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Daniel","family":"Joven\u2010Sancho","sequence":"additional","affiliation":[{"name":"Instituto de S\u00edntesis Qu\u00edmica y Cat\u00e1lisis Homog\u00e9nea (iSQCH) CSIC\u2010Universidad de Zaragoza  Pedro Cerbuna 12 Zaragoza 50009 Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Miguel","family":"Baya","sequence":"additional","affiliation":[{"name":"Instituto de S\u00edntesis Qu\u00edmica y Cat\u00e1lisis Homog\u00e9nea (iSQCH) CSIC\u2010Universidad de Zaragoza  Pedro Cerbuna 12 Zaragoza 50009 Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Noel","family":"Nebra","sequence":"additional","affiliation":[{"name":"Laboratoire H\u00e9t\u00e9rochimie Fondamentale et Appliqu\u00e9e (LHFA) Universit\u00e9 de Toulouse  CNRS. 118 Route de Narbonne Toulouse 31062 France"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,7,21]]},"reference":[{"key":"e_1_2_8_1_1","first-page":"1","volume-title":"Silver Catalysis in Organic Synthesis","author":"Sivaguru P.","year":"2019"},{"key":"e_1_2_8_1_2","unstructured":"b)The Editors of Encyclopaedia Britannica \u201cSilver Encyclopedia Britannica\u201d can be found underhttps:\/\/www.britannica.com\/science\/silver 2025(accessed: 9thApril)."},{"key":"e_1_2_8_2_1","unstructured":"a) For uses and properties of Ag see the following websites and references cited therein:The Royal Society of Chemistry \u201cSilver\u201d can be found underhttps:\/\/periodic\u2010table.rsc.org\/element\/47\/silver 2025(accessed: 9thApril);"},{"key":"e_1_2_8_2_2","unstructured":"b)J.Bashyal \u201cSilver (Ag) Element: Amazing Properties Uses Effects\u201d can be found underhttps:\/\/scienceinfo.com\/silver\u2010ag\u2010element\u2010uses\u2010properties\/ 2025(accessed: 9thApril)."},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/aoc.3047"},{"key":"e_1_2_8_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2016.05.015"},{"key":"e_1_2_8_3_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201205923"},{"key":"e_1_2_8_4_1","first-page":"1","volume-title":"Encyclopedia of Inorganic and Bioinorganic Chemistry","author":"Mak T. 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