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This is the first ever report on trifluoromethylation using in situ generated N\u2010trifluoromethylpyridinium tetrafluoroborate as the CF\n                    <jats:sub>3<\/jats:sub>\n                    source under ball\u2010milling conditions. The present one\u2010pot transformation enabled direct trifluoromethylation of arylboronic acids and phenols to deliver the respective trifluoromethyl arenes and aryl trifluoromethyl ethers. It has also shown a remarkable compatibility toward aroyltrifluoroborates for the mechanochemical synthesis of aryl trifluoromethyl ketones. This method offers several advantages, including operational simplicity and broad substrate compatibility. Moreover, the current mechanochemical approach not only proceeds under sustainable conditions but also provides a practical route for the late\u2010stage modifications of related substrates to access the valuable fluorinated compounds.\n                  <\/jats:p>","DOI":"10.1002\/chem.202501705","type":"journal-article","created":{"date-parts":[[2025,6,25]],"date-time":"2025-06-25T08:48:58Z","timestamp":1750841338000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Ru\u2010Catalyzed Mechanochemical Trifluoromethylation of Arylboronic Acids and Phenols by in Situ\u2010Generated\u00a0\n                    <i>N<\/i>\n                    \u2010Trifluoromethylpyridinium Salt as CF\n                    <sub>3<\/sub>\n                    \u00a0Source"],"prefix":"10.1002","volume":"31","author":[{"given":"Satenik","family":"Mkrtchyan","sequence":"first","affiliation":[{"name":"Department of Chemistry, Faculty of Natural Sciences Matej Bel University  Tajovsk\u00e9ho 40 Banska Bystrica 97401 Slovakia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ji\u0159\u00ed","family":"Zapletal","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Faculty of Natural Sciences Matej Bel University  Tajovsk\u00e9ho 40 Banska Bystrica 97401 Slovakia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Manoj K.","family":"Saini","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Institute of Science Banaras Hindu University  Varanasi 221005 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eugene","family":"Karpun","sequence":"additional","affiliation":[{"name":"Life Chemicals Ukraine  Winston Churchill St. 5 Kyiv 02000 Ukraine"},{"name":"Interregional Academy of Personnel Management  Frometivska str., 2 Kyiv Ukraine"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vishal B.","family":"Purohit","sequence":"additional","affiliation":[{"name":"Department of Chemical Sciences, P. 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