{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,9]],"date-time":"2026-04-09T15:00:50Z","timestamp":1775746850370,"version":"3.50.1"},"reference-count":58,"publisher":"Wiley","issue":"72","license":[{"start":{"date-parts":[[2025,11,13]],"date-time":"2025-11-13T00:00:00Z","timestamp":1762992000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,11,13]],"date-time":"2025-11-13T00:00:00Z","timestamp":1762992000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2025,12,23]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Organic solids typically adopt close\u2010packed structures to maximize the weak intermolecular interactions. From this perspective, unraveling the conditions in which a seemingly close\u2010packed molecular solid undergoes guest\u2010induced phase transition and shows reversible guest inclusion\/desolvation behavior remains a challenge. An organic luminogen, 4\u2010hydroxy\u2010benzoic acid (2\u2010hydroxy\u2010naphthalen\u20101\u2010ylmethylene)\u2010hydrazide (\n                    <jats:bold>2N\u20104 OH<\/jats:bold>\n                    ), produced two types of solids, viz., the yellow emissive\n                    <jats:bold>C\u2010Y<\/jats:bold>\n                    form and the green emissive\n                    <jats:bold>C\u2010G<\/jats:bold>\n                    form, of which the latter form was isolated as N.N\u2010dimethylformamide (DMF) solvate. The green emissive\n                    <jats:bold>C\u2010G<\/jats:bold>\n                    phase exhibited distinctive responses under conditions of mechanical grinding and compression, which was evident from spectroscopic, thermal, and X\u2010ray diffraction measurements. Further, when infused with DMF vapor, the\n                    <jats:bold>C\u2010Y<\/jats:bold>\n                    form transformed into the green emissive metastable\n                    <jats:bold>C\u2010M<\/jats:bold>\n                    form, which was structurally similar to the metastable phase obtained from the\n                    <jats:bold>C\u2010G<\/jats:bold>\n                    form upon hydraulic compression. Subsequently, we explain the relation between the\n                    <jats:bold>C\u2010Y<\/jats:bold>\n                    and\n                    <jats:bold>C\u2010G<\/jats:bold>\n                    forms, obtained directly upon crystallization, and the metastable\n                    <jats:bold>C\u2010M<\/jats:bold>\n                    form and the\n                    <jats:bold>C\u2010G(M)<\/jats:bold>\n                    form obtained after mechanical stimulation.\n                  <\/jats:p>","DOI":"10.1002\/chem.202502360","type":"journal-article","created":{"date-parts":[[2025,11,13]],"date-time":"2025-11-13T13:39:14Z","timestamp":1763041154000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Unravelling the Mechano\u2010Responsive Solvent Inclusion Behaviour of a Luminescent Organic Solid"],"prefix":"10.1002","volume":"31","author":[{"given":"Dubarima","family":"Kashyap","sequence":"first","affiliation":[{"name":"Department of Chemistry (Water Research Laboratory) Gauhati University  Guwahati Assam 781014 India"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5941-6615","authenticated-orcid":false,"given":"Rupam J.","family":"Sarma","sequence":"additional","affiliation":[{"name":"Department of Chemistry (Water Research Laboratory) Gauhati University  Guwahati Assam 781014 India"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2025,11,13]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja403264c"},{"key":"e_1_2_8_2_1","volume-title":"Polymorphism in Molecular Crystals","author":"Bernstein 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