{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T14:35:48Z","timestamp":1786977348035,"version":"build-2736575974"},"reference-count":79,"publisher":"Wiley","issue":"62","license":[{"start":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T00:00:00Z","timestamp":1760313600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2025,11,6]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    A series of phosphorus compounds bearing the 4\u2010\n                    <jats:italic>tert<\/jats:italic>\n                    \u2010butyl\u20102,6\u2010bis(benzimidazol\u20102\u2010yl)benzene ligand (BZIMB) were prepared and fully characterized using spectroscopic methods, including X\u2010ray crystallography. Reaction of the P\n                    <jats:sup>III<\/jats:sup>\n                    compounds with electrophilic reagents led to P\n                    <jats:sup>V<\/jats:sup>\n                    compounds. Reaction with reducing reagents led to P\n                    <jats:sup>I<\/jats:sup>\n                    phosphinidenes. The phosphinidenes react with electrophilic reagents to generate new P\n                    <jats:sup>III<\/jats:sup>\n                    compounds. In contrast to topologically related compounds featuring labile P\u2500N bonds, the robust P\u2500C bond between the phosphorus center and the ligand prevents dissociation of the phosphorus atom during oxidation and reduction, showing the potential for small molecule activation and opening the door for future catalytic studies.\n                  <\/jats:p>","DOI":"10.1002\/chem.202502683","type":"journal-article","created":{"date-parts":[[2025,10,14]],"date-time":"2025-10-14T01:40:42Z","timestamp":1760406042000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Synthesis of P\n                    <sup>I<\/sup>\n                    , P\n                    <sup>III<\/sup>\n                    , and P\n                    <sup>V<\/sup>\n                    Compounds Supported by Bis(benzimidazole)Benzene"],"prefix":"10.1002","volume":"31","author":[{"ORCID":"https:\/\/orcid.org\/0009-0003-3945-6718","authenticated-orcid":false,"given":"Takahiko","family":"Ogawa","sequence":"first","affiliation":[{"name":"Department of Chemistry Dalhousie University  Halifax Nova Scotia B3H 4R2 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5861-242X","authenticated-orcid":false,"given":"Michael A.","family":"Land","sequence":"additional","affiliation":[{"name":"Department of Chemistry Dalhousie University  Halifax Nova Scotia B3H 4R2 Canada"},{"name":"Department of Chemistry &amp; Physics Mount Saint Vincent University  Halifax Nova Scotia B3M 2J6 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5602-8059","authenticated-orcid":false,"given":"Katherine N.","family":"Robertson","sequence":"additional","affiliation":[{"name":"Department of Chemistry Saint Mary's University  Halifax Nova Scotia B3H 3C3 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0574-1524","authenticated-orcid":false,"given":"Charles L. 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