{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,9]],"date-time":"2026-04-09T15:00:57Z","timestamp":1775746857989,"version":"3.50.1"},"reference-count":27,"publisher":"Wiley","issue":"72","license":[{"start":{"date-parts":[[2025,11,13]],"date-time":"2025-11-13T00:00:00Z","timestamp":1762992000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,11,13]],"date-time":"2025-11-13T00:00:00Z","timestamp":1762992000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100003392","name":"Natural Science Foundation of Fujian Province","doi-asserted-by":"publisher","award":["2024J01192"],"award-info":[{"award-number":["2024J01192"]}],"id":[{"id":"10.13039\/501100003392","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22371279"],"award-info":[{"award-number":["22371279"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22271282"],"award-info":[{"award-number":["22271282"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2025,12,23]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Research on the synthesis and stabilization of air\u2010stable monovalent zinc (Zn\n                    <jats:sup>+<\/jats:sup>\n                    ) species under mild conditions remains relatively unexplored. This article reports the synthesis of a new zinc coordination polymer, [Zn\n                    <jats:sub>2<\/jats:sub>\n                    (PA)\n                    <jats:sub>4<\/jats:sub>\n                    (bipy)\n                    <jats:sub>2<\/jats:sub>\n                    ]\n                    <jats:italic>\n                      <jats:sub>n<\/jats:sub>\n                    <\/jats:italic>\n                    \u00b7\n                    <jats:italic>n<\/jats:italic>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    O (\n                    <jats:bold>1<\/jats:bold>\n                    ) (PA\u00a0=\u00a0propionate; bipy\u00a0=\u00a0bipyridine), which generates stable Zn\n                    <jats:sup>+<\/jats:sup>\n                    species upon photoirradiation under ambient conditions. Compound\n                    <jats:bold>1<\/jats:bold>\n                    features a metalloviologen structure built by 1\u2010D ladder\u2010like chains. Upon Xe lamp irradiation, it changes from colorless to light brown, which is accompanied by the emergence of new electron absorption bands assigned to bipy radical anions and Zn\n                    <jats:sup>+<\/jats:sup>\n                    species by UV\u2013vis and EPR tests. PXRD, Raman, and IR analyses indicate that the crystalline framework remains but distortion happens during photoirradiation. The photoinduced Zn\n                    <jats:sup>+<\/jats:sup>\n                    species remains stable under ambient conditions for at least 7 days. This work demonstrates that air\u2010stable Zn\n                    <jats:sup>+<\/jats:sup>\n                    species can be easily prepared through the coordination assembly of Zn\n                    <jats:sup>2+<\/jats:sup>\n                    ion, carboxylate and bipyridine and further light stimulation, which will help to understand the chemical bonding nature or find catalytic and other applications of Zn\n                    <jats:sup>+<\/jats:sup>\n                    \u2010based materials.\n                  <\/jats:p>","DOI":"10.1002\/chem.202502955","type":"journal-article","created":{"date-parts":[[2025,11,13]],"date-time":"2025-11-13T08:03:43Z","timestamp":1763021023000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Light\u2010Driven Generation of Air\u2010stable Zn(I) Under Ambient Conditions"],"prefix":"10.1002","volume":"31","author":[{"given":"Hong\u2010Zhi","family":"Xiao","sequence":"first","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian 350108 P. R. China"},{"name":"College of Chemistry Fuzhou University  Fuzhou Fujian 350108 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mian\u2010He","family":"Xu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian 350108 P. R. China"},{"name":"College of Chemistry Fuzhou University  Fuzhou Fujian 350108 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Li\u2010Zhen","family":"Cai","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian 350108 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2400-719X","authenticated-orcid":false,"given":"Ming\u2010Sheng","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian 350108 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7450-9702","authenticated-orcid":false,"given":"Guo\u2010Cong","family":"Guo","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian 350108 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2025,11,13]]},"reference":[{"key":"e_1_2_9_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.7b03423"},{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1956"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1188267"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja103843d"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201102320"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201503730"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202111683"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja400757c"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp400331m"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevA.25.737"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp963963m"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja0343757"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jssc.2013.03.027"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5DT01088H"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1101356"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201801227"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms7331"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201705173"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC03354G"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic402182j"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3QI00436H"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c10183"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201201915"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1010\u20106030(98)00327\u2010X"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic8024099"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/j29710002406"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/jrs.1250170306"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202502955","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.202502955","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202502955","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,4,9]],"date-time":"2026-04-09T14:25:40Z","timestamp":1775744740000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.202502955"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,11,13]]},"references-count":27,"journal-issue":{"issue":"72","published-print":{"date-parts":[[2025,12,23]]}},"alternative-id":["10.1002\/chem.202502955"],"URL":"https:\/\/doi.org\/10.1002\/chem.202502955","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,11,13]]},"assertion":[{"value":"2025-09-25","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-11-06","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-11-13","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e02955"}}