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Herein, we propose the use of double\u2010vacancy halide perovskites as precursors for engineering highly crystalline and small platinum nanoparticles (&lt;\u00a03\u00a0nm) under simulated sunlight irradiation, using low concentration of methanol as sacrificial agent at room temperature. The formation of Pt NP was dependent on the methanol concentration impacting in the final Pt particle size distribution and time formation. After purification, this narrow sized Pt NP were employed for the methanol reforming reaction, showing excellent activity after 4\u00a0h and high selectivity toward hydrogen production (4.18\u00a0mmol\u00b7h\n                    <jats:sup>\u22121<\/jats:sup>\n                    of H\n                    <jats:sub>2<\/jats:sub>\n                    ), along with other carbon products such as CO (2.26\u00a0mmol\u00b7h\n                    <jats:sup>\u22121<\/jats:sup>\n                    ), CH\n                    <jats:sub>4<\/jats:sub>\n                    (0.54\u00a0mmol\u00b7h\n                    <jats:sup>\u22121<\/jats:sup>\n                    ), CO\n                    <jats:sub>2<\/jats:sub>\n                    (0.28\u00a0mmol\u00b7h\n                    <jats:sup>\u22121<\/jats:sup>\n                    ), and C\n                    <jats:sub>2<\/jats:sub>\n                    species (0.17\u00a0mmol\u00b7h\n                    <jats:sup>\u22121<\/jats:sup>\n                    ).\n                  <\/jats:p>","DOI":"10.1002\/chem.202503192","type":"journal-article","created":{"date-parts":[[2026,5,12]],"date-time":"2026-05-12T04:19:21Z","timestamp":1778559561000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Sunlight\u2010Driven Green Synthesis of Platinum Nanoparticles From Double\u2010Vacancy Halide Perovskite Precursors for Methanol Reforming"],"prefix":"10.1002","volume":"32","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3150-5004","authenticated-orcid":false,"given":"Kevin","family":"Mego","sequence":"first","affiliation":[{"name":"Instituto de Tecnolog\u00eda Qu\u00edmica (ITQ) Consejo Superior de Investigaciones Cient\u00edficas\u2010Universitat Polit\u00e8cnica de Val\u00e8ncia  Valencia 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