{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,24]],"date-time":"2026-04-24T11:39:02Z","timestamp":1777030742864,"version":"3.51.4"},"reference-count":46,"publisher":"Wiley","issue":"15","license":[{"start":{"date-parts":[[2026,2,5]],"date-time":"2026-02-05T00:00:00Z","timestamp":1770249600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,2,5]],"date-time":"2026-02-05T00:00:00Z","timestamp":1770249600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100004608","name":"Natural Science Foundation of Jiangsu Province","doi-asserted-by":"publisher","award":["BK20221485"],"award-info":[{"award-number":["BK20221485"]}],"id":[{"id":"10.13039\/501100004608","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22172068"],"award-info":[{"award-number":["22172068"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22372001"],"award-info":[{"award-number":["22372001"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2026,4,22]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The efficient separation and transfer of photogenerated charge carriers remain a difficult challenge in photocatalysis. While the heterojunctions are an effective strategy for promoting photogenerated charge separation, inefficient migration at the interface often hinders the development. Herein, we report a core\u2010shell organic\u2010inorganic hybrid system, TiO\n                    <jats:sub>2<\/jats:sub>\n                    @3\u2010aminophenol formaldehyde resin spheres ({001}\u2010TiO\n                    <jats:sub>2<\/jats:sub>\n                    @APF) for photocatalytic water treatment. The {001}\u2010TiO\n                    <jats:sub>2<\/jats:sub>\n                    @APF heterojunction achieves a 100% degradation efficiency of glyphosate in 6\u00a0h with a reaction rate constant of 0.0068 min\n                    <jats:sup>\u22121<\/jats:sup>\n                    , which is 6.2 times that of APF (0.0011 min\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) and 1.3 times that of bare TiO\n                    <jats:sub>2<\/jats:sub>\n                    (0.0051 min\n                    <jats:sup>\u22121<\/jats:sup>\n                    ). XPS analysis confirms the formation of Ti\u2010O\u2010C covalent bonds at the organic\u2010inorganic interface, which effectively addresses the charge transport challenge and facilitates rapid carrier migration across the heterojunction. This work underscores the importance of atomic\u2010level interfacial engineering in constructing high\u2010efficiency inorganic\u2010organic photocatalysts for sustainable water purification.\n                  <\/jats:p>","DOI":"10.1002\/chem.202503212","type":"journal-article","created":{"date-parts":[[2026,2,5]],"date-time":"2026-02-05T12:57:50Z","timestamp":1770296270000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Core Shell {001}\u2010TiO\n                    <sub>2<\/sub>\n                    @APF Heterojunction Photocatalysts for Enhanced Water Treatment Performance"],"prefix":"10.1002","volume":"32","author":[{"given":"Gaomin","family":"Ning","sequence":"first","affiliation":[{"name":"School of New Energy Nanjing University of Science and Technology  Jiangyin China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yuanyuan","family":"Jiang","sequence":"additional","affiliation":[{"name":"School of New Energy Nanjing University of Science and Technology  Jiangyin China"},{"name":"Agricultural Photocatalysis Laboratory School of Materials and Chemistry &amp; School of Plant Protection Anhui Agricultural University  Hefei China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chunna","family":"Zhu","sequence":"additional","affiliation":[{"name":"School of New Energy Nanjing University of Science and Technology  Jiangyin China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lijiang","family":"Ge","sequence":"additional","affiliation":[{"name":"Agricultural Photocatalysis Laboratory School of Materials and Chemistry &amp; School of Plant Protection Anhui Agricultural University  Hefei China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2314-2856","authenticated-orcid":false,"given":"Sheng","family":"Ye","sequence":"additional","affiliation":[{"name":"Agricultural Photocatalysis Laboratory School of Materials and Chemistry &amp; School of Plant Protection Anhui Agricultural University  Hefei China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jing","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of New Energy Nanjing University of Science and Technology  Jiangyin China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2026,2,5]]},"reference":[{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2023.123262"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3EY00047H"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202212243"},{"key":"e_1_2_6_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b10662"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c00802"},{"key":"e_1_2_6_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3TA13793G"},{"key":"e_1_2_6_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.egypro.2017.07.117"},{"key":"e_1_2_6_9_1","first-page":"1231","article-title":": Challenges and Opportunities","volume":"2","author":"Hern\u00e1ndez\u2010Alonso M. D.","year":"2009","journal-title":"Energy & Environmental Science"},{"key":"e_1_2_6_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jece.2017.07.080"},{"key":"e_1_2_6_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2019.123918"},{"key":"e_1_2_6_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jenvman.2018.02.064"},{"key":"e_1_2_6_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2018.10.219"},{"key":"e_1_2_6_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/asia.201200474"},{"key":"e_1_2_6_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2017.05.042"},{"key":"e_1_2_6_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijhydene.2019.07.241"},{"key":"e_1_2_6_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2021.130945"},{"key":"e_1_2_6_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202212486"},{"key":"e_1_2_6_19_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-35875-9"},{"key":"e_1_2_6_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202209646"},{"key":"e_1_2_6_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2021.129476"},{"key":"e_1_2_6_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2021.128555"},{"key":"e_1_2_6_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2021.120802"},{"key":"e_1_2_6_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2020.119785"},{"key":"e_1_2_6_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202200172"},{"key":"e_1_2_6_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3EN00077J"},{"key":"e_1_2_6_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2022.155346"},{"key":"e_1_2_6_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1872-2067(20)63593-8"},{"key":"e_1_2_6_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2TC04284C"},{"key":"e_1_2_6_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ceramint.2021.02.019"},{"key":"e_1_2_6_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9RA07562C"},{"key":"e_1_2_6_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2018.10.023"},{"key":"e_1_2_6_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2023.122780"},{"key":"e_1_2_6_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202303638"},{"key":"e_1_2_6_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201102011"},{"key":"e_1_2_6_36_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3NJ00926B"},{"key":"e_1_2_6_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2015.07.009"},{"key":"e_1_2_6_38_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41598-023-36486-6"},{"key":"e_1_2_6_39_1","first-page":"926","article-title":"Surface Modification of Hollow Structure TiO2 Nanospheres for Enhanced Photocatalytic Hydrogen Evolution","volume":"13","author":"Ning G.","year":"2023","journal-title":"NMs"},{"key":"e_1_2_6_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2023.142850"},{"key":"e_1_2_6_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2022.02.034"},{"key":"e_1_2_6_42_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4RA10572A"},{"key":"e_1_2_6_43_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4GC02298J"},{"key":"e_1_2_6_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202303642"},{"key":"e_1_2_6_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202207173"},{"key":"e_1_2_6_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2019.10.064"},{"key":"e_1_2_6_47_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2019.02.100"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202503212","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.202503212","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202503212","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,4,24]],"date-time":"2026-04-24T10:49:51Z","timestamp":1777027791000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.202503212"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,2,5]]},"references-count":46,"journal-issue":{"issue":"15","published-print":{"date-parts":[[2026,4,22]]}},"alternative-id":["10.1002\/chem.202503212"],"URL":"https:\/\/doi.org\/10.1002\/chem.202503212","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,2,5]]},"assertion":[{"value":"2025-10-22","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-12-19","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-02-05","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e03212"}}