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We fabricate phosphorus\u2010doped carbon nanotubes (P\u2010CNTs) by a simple, low\u2010cost vapor\u2010diffusion route and use them as sulfur\u2010host cathodes. Phosphorus incorporation and increased defect density create abundant sites for chemisorption and catalytic conversion of polysulfides, suppressing the shuttle and accelerating kinetics. The conductive, tubular architecture also preserves electron pathways and buffers volume changes, enabling fast charge transfer and structural integrity during cycling. The P\u2010CNTs cathodes deliver an initial specific capacity of 1153.8 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 0.2 C and sustain 500 cycles at 1.0 C with an average per\u2010cycle decay of only 0.095%. Under a high sulfur loading of 6.55\u00a0mg cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , an areal capacity of 7.73 mAh cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    at 0.2 C is achieved with 66.1% retention after 100 cycles. Spectroscopic and electrochemical analyses indicate strong adsorption of sulfur species on P\u2010CNTs, effectively anchoring LiPSs intermediates and improving coulombic efficiency. These results establish P\u2010CNTs as effective, scalable cathode hosts for long\u2010life, high\u2010loading Li\u2010S batteries and highlight a practical strategy coupling physical confinement with catalytic regulation of polysulfides.\n                  <\/jats:p>","DOI":"10.1002\/chem.202503372","type":"journal-article","created":{"date-parts":[[2026,2,18]],"date-time":"2026-02-18T18:27:30Z","timestamp":1771439250000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Polar Phosphorus Sites in CNTs Suppress Polysulfide Shuttle and Accelerate Conversion in Li\u2010S Cathodes"],"prefix":"10.1002","volume":"32","author":[{"given":"Xitong","family":"Sheng","sequence":"first","affiliation":[{"name":"Xi'an Key Laboratory of Functional Organic Porous Materials, School of Chemistry and Chemical Engineering Northwestern Polytechnical University  Xi'an PR 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