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Both linear and branched\u2010allyl moieties were incorporated using either same or different nucleophiles through successive chemoselective allylations on alkenyl\u2010keto\u2010imines in a single operation. Notably, in the whole reaction sequence, while the first allyl nucleophile reacts selectively on ketone, the second one reacts on imine. Control experiments and DFT calculations supported the proposed reaction mechanism.<\/jats:p>","DOI":"10.1002\/chem.202503385","type":"journal-article","created":{"date-parts":[[2025,12,29]],"date-time":"2025-12-29T13:58:46Z","timestamp":1767016726000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Boron\u2010Enolate Enabled Chemoselective Twofold Allylation of Alkenyl\u2010Keto\u2010Imines Using Allylboronic Acids: Asymmetric Construction of Nonadjacent Stereocenters"],"prefix":"10.1002","volume":"32","author":[{"given":"Ganesh","family":"Karan","sequence":"first","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Kharagpur  Kharagpur 721302 India"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Susanta","family":"Bhunia","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Kharagpur  Kharagpur 721302 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