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Metal promoters, particularly platinum, have been used to enhance In\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    activity toward methanol synthesis, but their behavior under atmospheric conditions remains poorly understood. Here, we investigate the pressure\u2010dependent reactivity of platinum\u2010promoted In\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    (Pt\/In\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    ). Pt\/In\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    is highly active for the reverse water gas shift (RWGS) reaction at 0.1\u00a0MPa, while achieving excellent methanol selectivity at elevated pressures. Catalyst characterization combined with density functional theory (DFT) calculations indicates that CO formation at low pressure proceeds via a redox mechanism, whereas elevated pressure stabilizes CO* intermediates and promotes their hydrogenation to methanol. These results highlight the intrinsic pressure\u2010tunable reactivity of Pt\/In\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    and provide mechanistic insight for controlling product selectivity in CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation.\n                  <\/jats:p>","DOI":"10.1002\/chem.202503479","type":"journal-article","created":{"date-parts":[[2026,3,13]],"date-time":"2026-03-13T17:20:27Z","timestamp":1773422427000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Pressure\u2010Induced Selectivity Change of Pt\/In\n                    <sub>2<\/sub>\n                    O\n                    <sub>3<\/sub>\n                    for CO\n                    <sub>2<\/sub>\n                    Hydrogenation: From Methanol Synthesis to CO Formation"],"prefix":"10.1002","volume":"32","author":[{"given":"Yuning","family":"Ma","sequence":"first","affiliation":[{"name":"School of Chemical Engineering and Technology Tianjin University  Tianjin China"},{"name":"Collaborative Innovation Center of Chemical Science &amp; Engineering Tianjin University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shilong","family":"Xiong","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Technology Tianjin University  Tianjin China"},{"name":"Collaborative Innovation Center of Chemical Science &amp; Engineering Tianjin University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kaihang","family":"Sun","sequence":"additional","affiliation":[{"name":"College of Chemistry Zhengzhou University  Zhengzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chang\u2010jun","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Technology Tianjin University  Tianjin China"},{"name":"Collaborative Innovation Center of Chemical Science &amp; Engineering Tianjin University  Tianjin China"},{"name":"State Key Laboratory of Synthetic Biology, Tianjin University  Tianjin 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