{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,1]],"date-time":"2026-09-01T10:26:51Z","timestamp":1788258411089,"version":"build-2803163510"},"reference-count":43,"publisher":"Wiley","issue":"15","license":[{"start":{"date-parts":[[2026,2,5]],"date-time":"2026-02-05T00:00:00Z","timestamp":1770249600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,2,5]],"date-time":"2026-02-05T00:00:00Z","timestamp":1770249600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22475127"],"award-info":[{"award-number":["22475127"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22133005"],"award-info":[{"award-number":["22133005"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2026,4,22]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The spinel compound LiNi\n                    <jats:sub>0.5<\/jats:sub>\n                    Mn\n                    <jats:sub>1.5<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    (LNMO) has attracted increasing attention as a potential cathode material for high\u2010energy lithium\u2010ion batteries (LIBs) of the next generation. Despite its attractive properties, LNMO suffers from transition\u2010metal ion dissolution and pronounced capacity fading, which significantly limit its practical implementation. To address these limitations, Zn is introduced into the LNMO structure to prepare Zn\u2010doped LNMO, designed to stabilize the 16c and 8a sites and thus improve its electrochemical performance. This doping approach improves the structural robustness of LNMO and significantly suppresses Mn dissolution during electrochemical cycling. Even after 1000 cycles at a current rate of 1 C (1 C = 147\u00a0mA g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ), the Zn\u2010LNMO sample maintains 81.2% of its original capacity, demonstrating substantially improved capacity retention. Moreover, the Zn\u2010LNMO electrode maintains 98.8% of its initial voltage after 1000 cycles, and the corresponding average decline in voltage is as low as 0.06\u00a0mV for each cycle. This study establishes an atomically engineered doping concept that can be generalized to various cathode systems and serves as an effective guideline for designing high\u2010performance LIBs.\n                  <\/jats:p>","DOI":"10.1002\/chem.202503553","type":"journal-article","created":{"date-parts":[[2026,2,6]],"date-time":"2026-02-06T07:49:05Z","timestamp":1770364145000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Mitigated Mn Dissolution and Improved Cycling Stability of LiNi\n                    <sub>0.5<\/sub>\n                    Mn\n                    <sub>1.5<\/sub>\n                    O\n                    <sub>4<\/sub>\n                    Spinel Cathodes by Zinc Doping"],"prefix":"10.1002","volume":"32","author":[{"ORCID":"https:\/\/orcid.org\/0009-0006-4618-9998","authenticated-orcid":false,"given":"Jing\u2010Zhe","family":"Wan","sequence":"first","affiliation":[{"name":"State Key Laboratory of Synergistic Chem\u2010Bio Synthesis School of Chemistry and Chemical Engineering Shanghai Jiao Tong University  Shanghai P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chao","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Synergistic Chem\u2010Bio Synthesis School of Chemistry and Chemical Engineering Shanghai Jiao Tong University  Shanghai P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liang","family":"Gao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Synergistic Chem\u2010Bio Synthesis School of Chemistry and Chemical Engineering Shanghai Jiao Tong University  Shanghai P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pei\u2010Long","family":"Lee","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Synergistic Chem\u2010Bio Synthesis School of Chemistry and Chemical Engineering Shanghai Jiao Tong University  Shanghai P. R. 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