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Herein, a high\u2010performance confined catalyst through a simple one\u2010pot method is developed, denoted as HPW@ZIF\u20108. The phosphotungstic acid is encapsulated and confined within the pores of the ZIF\u20108 framework, achieving ambient temperature catalytic oxidation of aromatic sulfides to high\u2010value sulfones. The induced charge shift in the confined catalysis is observed, as the weak interaction force between the phosphorus\u2010tungsten structure and Zn center, strengthening the catalytic oxidation performance. Under unheated conditions, the hydrogen peroxide utilization rate and activity of the catalyst at ambient temperature are both greater than 97.0%. In addition, the confined catalysts exhibit good cycling performance after 10 cycles, attributed to the highly matched host and guest, with only 0.2% HPW loss. Above all, this work offers new insights for the green, low\u2010energy consumption, and high\u2010value utilization of diesel fuel.<\/jats:p>","DOI":"10.1002\/chem.202503563","type":"journal-article","created":{"date-parts":[[2026,3,10]],"date-time":"2026-03-10T03:56:46Z","timestamp":1773115006000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis of Confined HPW@ZIF\u20108 for Ambient Catalytic Oxidation of Aromatic Sulfides in Diesel"],"prefix":"10.1002","volume":"32","author":[{"given":"Lai","family":"Wei","sequence":"first","affiliation":[{"name":"College of Chemical Engineering and Environment State Key Laboratory of Heavy Oil Processing China University of Petroleum\u2010Beijing  Beijing PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhendong","family":"Yu","sequence":"additional","affiliation":[{"name":"College of Chemical Engineering and Environment State Key Laboratory 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