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The complexes [Cu(PPh\n 3<\/jats:sub>\n ){Ph\n 3<\/jats:sub>\n B(3\u2010(CF\n 3<\/jats:sub>\n )Pz)}] (\n 7<\/jats:bold>\n ), [Cu(PPh\n 3<\/jats:sub>\n ){Ph\n 2<\/jats:sub>\n B(3\u2010(CF\n 3<\/jats:sub>\n )Pz)\n 2<\/jats:sub>\n }] (\n 8<\/jats:bold>\n ), [Cu(PPh\n 3<\/jats:sub>\n ){PhB(3\u2010(CF\n 3<\/jats:sub>\n )Pz)\n 3<\/jats:sub>\n }] (\n 9<\/jats:bold>\n ), [Cu(PPh\n 3<\/jats:sub>\n ){Ph\n 3<\/jats:sub>\n B(6\u2010(CF\n 3<\/jats:sub>\n )Py)}] (\n 10<\/jats:bold>\n ), [Cu(PPh\n 3<\/jats:sub>\n ){Ph\n 2<\/jats:sub>\n B(6\u2010(CF\n 3<\/jats:sub>\n )Py)\n 2<\/jats:sub>\n }] (\n 11<\/jats:bold>\n ) and [Cu(PPh\n 3<\/jats:sub>\n ){PhB(6\u2010(CF\n 3<\/jats:sub>\n )Py)\n 3<\/jats:sub>\n }] (\n 12<\/jats:bold>\n ) were fully characterized by multinuclear NMR spectroscopy, electrochemistry, and single\u2010crystal X\u2010ray diffraction. All compounds display trigonal\u2010planar copper centers, with mono(pyrazolyl)\u2010 and mono(pyridyl)borate complexes\n 7<\/jats:bold>\n and\n 10<\/jats:bold>\n exhibiting an unusual pseudo\u2010\u03ba\n 2<\/jats:sup>\n coordination supported by Cu\u2022\u2022\u2022C(ipso) interactions. Cyclic voltammetry revealed complex multielectron oxidation behavior, with poly(pyridyl)borate systems undergoing Cu(I)\u2192Cu(II) oxidation at relatively lower potentials than their pyrazolyl analogues, consistent with stronger pyridyl \u03c3\u2010donation. We also conducted efficacy tests on newly synthesized copper(I) complexes and related free ligands against a panel of human cancer cell lines from various solid tumors to explore relevant structure\u2010activity relationships. Studies on molecular target interaction, cellular redox modulation, and cell\u2010death pathways, have also been conducted to elucidate their mode(s) of action. Altogether, these results highlight how fluorinated scorpionate ligand design enable fine tuning of structure and properties of copper(I) complexes and underscore their promise as anticancer candidates.\n <\/jats:p>","DOI":"10.1002\/chem.70848","type":"journal-article","created":{"date-parts":[[2026,3,8]],"date-time":"2026-03-08T15:35:53Z","timestamp":1772984153000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Structural and Biological Insights Into Copper(I) Phosphane Complexes With Boron\u2010Phenylated Poly(3\u2010(CF\n 3<\/sub>\n )Pyrazolyl)\u2010 and Poly(6\u2010(CF\n 3<\/sub>\n )\u20102\u2010pyridyl)\u2010Borates"],"prefix":"10.1002","volume":"32","author":[{"given":"Vo Quang Huy","family":"Phan","sequence":"first","affiliation":[{"name":"Department of Chemistry and Biochemistry The University of Texas at Arlington Arlington Texas USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0002-8969-0900","authenticated-orcid":false,"given":"Jo\u2019","family":"Del Gobbo","sequence":"additional","affiliation":[{"name":"School of Science and Technology Chemistry Division University of Camerino Camerino Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mukundam","family":"Vanga","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry The University of Texas at Arlington Arlington Texas USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Deepika V.","family":"Karade","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry The University of Texas at Arlington Arlington Texas USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cristina","family":"Marzano","sequence":"additional","affiliation":[{"name":"Department of Pharmaceutical and Pharmacological Sciences University of Padova Padova Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Valentina","family":"Gandin","sequence":"additional","affiliation":[{"name":"Department of Pharmaceutical and Pharmacological Sciences University of Padova Padova Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Laura","family":"Rigon","sequence":"additional","affiliation":[{"name":"Department of Medicine University of Padova Padova Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Carlo","family":"Santini","sequence":"additional","affiliation":[{"name":"School of Science and Technology Chemistry Division University of Camerino Camerino Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5020-1730","authenticated-orcid":false,"given":"Maura","family":"Pellei","sequence":"additional","affiliation":[{"name":"School of Science and Technology Chemistry Division University of Camerino Camerino Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2362-1331","authenticated-orcid":false,"given":"H. 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