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Control experiments indicated that the reaction proceeds through a linear rather than a branched fluoroalkene intermediate, and further incorporates the C2 and C3 atoms of the\n                    <jats:italic>gem<\/jats:italic>\n                    \u2010F\n                    <jats:sub>2<\/jats:sub>\n                    CP motif into the furan skeletons selectively. Besides, the synthetic utility of this protocol was demonstrated through the modification of bioactive molecules and transformations of furan products into 1,4\u2010epoxynaphthalene derivatives.\n                  <\/jats:p>","DOI":"10.1002\/chem.70879","type":"journal-article","created":{"date-parts":[[2026,3,13]],"date-time":"2026-03-13T08:36:31Z","timestamp":1773390991000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Palladium\u2010Catalyzed Ring\u2010Opening\/Defluorinative Annulation of\n                    <i>gem<\/i>\n                    \u2010Difluorocyclopropanes With\n                    <i>\u03b2<\/i>\n                    \u2010Keto Sulfones: Synthesis of Multi\u2010Substituted Furans"],"prefix":"10.1002","volume":"32","author":[{"given":"Wanqing","family":"Lu","sequence":"first","affiliation":[{"name":"Key Laboratory of Advanced Light Conversion Materials and Biophotonics School of Chemistry and Life 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