{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,9]],"date-time":"2026-10-09T17:10:13Z","timestamp":1791565813432,"version":"4.3.4"},"reference-count":36,"publisher":"Wiley","issue":"20","license":[{"start":{"date-parts":[[2026,3,14]],"date-time":"2026-03-14T00:00:00Z","timestamp":1773446400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,3,14]],"date-time":"2026-03-14T00:00:00Z","timestamp":1773446400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2026,5,27]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Thiazolinochlorin compounds bearing sulfoxide and sulfone moieties were prepared by selective sulfur\u2010oxidation with\n                    <jats:italic>m<\/jats:italic>\n                    \u2010chloroperoxybenzoic acid. The oxidation state of the sulfur atom directly affected the optical properties of the thiazolinochlorin compounds, which were investigated through computational calculations. The structures of zinc complexes of these compounds were drastically changed by the oxidation state of the sulfur atom. Notably, nonoxidized thiazolinochlorin afforded a \u03c0\u2010cation complex with elimination of the alkoxy group. The detailed structure and optical properties of the complexes in solution were investigated and compared with those of neutral zinc complexes derived from sulfoxide and sulfone compounds. Furthermore, the \u03c0\u2010cation complex underwent self\u2010aggregation, enabling the absorption of near\u2010infrared light.\n                  <\/jats:p>","DOI":"10.1002\/chem.70880","type":"journal-article","created":{"date-parts":[[2026,3,14]],"date-time":"2026-03-14T13:14:57Z","timestamp":1773494097000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Sulfur\u2010Oxidation of Thiazolinochlorin for Controlling Optical Properties and Structures of Metal Complexes: Expansion to \u03c0\u2010Cation Species"],"prefix":"10.1002","volume":"32","author":[{"given":"Takeo","family":"Nakano","sequence":"first","affiliation":[{"name":"Graduate School of Science and Technology Shinshu University  Matsumoto Nagano Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shu","family":"Miyawaki","sequence":"additional","affiliation":[{"name":"Graduate School of Science and Technology Shinshu University  Matsumoto Nagano Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Akifumi","family":"Sumida","sequence":"additional","affiliation":[{"name":"Faculty of Molecular Chemistry and Engineering Kyoto Institute of Technology  Kyoto Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shin","family":"Ogasawara","sequence":"additional","affiliation":[{"name":"Graduate School of Life Sciences Ritsumeikan University  Kusatsu Shiga Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yusuke","family":"Miyake","sequence":"additional","affiliation":[{"name":"Faculty of Molecular Chemistry and Engineering Kyoto Institute of Technology  Kyoto Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Atom","family":"Hamasaki","sequence":"additional","affiliation":[{"name":"Graduate School of Science and Technology Shinshu University  Matsumoto Nagano Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hiroaki","family":"Imoto","sequence":"additional","affiliation":[{"name":"Faculty of Molecular Chemistry and Engineering Kyoto Institute of Technology  Kyoto Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kensuke","family":"Naka","sequence":"additional","affiliation":[{"name":"Faculty of Molecular Chemistry and Engineering Kyoto Institute of Technology  Kyoto Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hitoshi","family":"Tamiaki","sequence":"additional","affiliation":[{"name":"Graduate School of Life Sciences Ritsumeikan University  Kusatsu Shiga Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,3,14]]},"reference":[{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jphotochemrev.2006.04.002"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8TA06392C"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.dyepig.2017.05.001"},{"key":"e_1_2_6_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0TB00083C"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo300963m"},{"key":"e_1_2_6_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0040\u20104039(98)00659\u20105"},{"key":"e_1_2_6_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0ob00920b"},{"key":"e_1_2_6_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3ob40138c"},{"key":"e_1_2_6_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2007.06.002"},{"key":"e_1_2_6_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/ol0622763"},{"key":"e_1_2_6_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja076709o"},{"key":"e_1_2_6_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/b923220f"},{"key":"e_1_2_6_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201201399"},{"key":"e_1_2_6_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9NJ01113G"},{"key":"e_1_2_6_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.9b11889"},{"key":"e_1_2_6_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/bc015547x"},{"key":"e_1_2_6_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo052334i"},{"key":"e_1_2_6_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2020.213340"},{"key":"e_1_2_6_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/9781119129301.ch17"},{"key":"e_1_2_6_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.1c03001"},{"key":"e_1_2_6_22_1","doi-asserted-by":"publisher","DOI":"10.1142\/S1088424622500110"},{"key":"e_1_2_6_23_1","doi-asserted-by":"publisher","DOI":"10.1142\/S1088424616300147"},{"key":"e_1_2_6_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.3c00088"},{"key":"e_1_2_6_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202218892"},{"key":"e_1_2_6_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2014.08.014"},{"key":"e_1_2_6_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsaem.8b00380"},{"key":"e_1_2_6_28_1","unstructured":"Deposition number 2505766 (for1\u2010Zn) contain the supplementary crystallographic data for this paper These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum Karlsruhe Access Structures service."},{"key":"e_1_2_6_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja026089l"},{"key":"e_1_2_6_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1099\u20100682(200003)2000:3<447::AID\u2010EJIC447>3.0.CO;2\u2010Z"},{"key":"e_1_2_6_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja01029a040"},{"key":"e_1_2_6_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00714a038"},{"key":"e_1_2_6_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar50073a005"},{"key":"e_1_2_6_34_1","unstructured":"THF containing a small amount of 2 6\u2010di\u2010tert\u2010butyl\u20104\u2010hydroxytoluene (BHT) as an antioxidant was used because BHT\u2010free THF led to decomposition of1\u2010Zn."},{"key":"e_1_2_6_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo3010342"},{"key":"e_1_2_6_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202112456"},{"key":"e_1_2_6_37_1","unstructured":"After removal of solvent from a EtOH solution of1\u2010Zn 1H NMR spectrum of1\u2010Znin CDCl3was checked Although the NMR spectrum exhibited a small amount of by\u2010product which could be ascribed to EtO\u2010adduct at thiazoline ring most of the structure of the \u03c0\u2010cation structure1\u2010Znwas maintained."}],"container-title":["Chemistry \u2013 A European 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