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These extremely electron\u2010poor gold complexes are found to be susceptible to aryl metalation reactions with unfunctionalized aryls such as benzene and toluene. Subsequent addition of soluble halide sources allows for the synthesis of aryl halides.<\/jats:p>","DOI":"10.1002\/chem.70920","type":"journal-article","created":{"date-parts":[[2026,3,27]],"date-time":"2026-03-27T12:46:13Z","timestamp":1774615573000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis and Reactivity of Extremely Electron\u2010Poor Au(III) Complexes Bearing OTf\n                    <sup>\u2212<\/sup>\n                    or NTf\n                    <sub>2<\/sub>\n                    <sup>\u2212<\/sup>\n                    Ligands"],"prefix":"10.1002","volume":"32","author":[{"given":"Lachlan","family":"Barwise","sequence":"first","affiliation":[{"name":"Department of Biochemistry and Chemistry, La Trobe Institute for Molecular Science La Trobe University  Melbourne Victoria 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