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The photocatalytic CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction reaction (CO\n                    <jats:sub>2<\/jats:sub>\n                    RR) in gas\u2010solid phase systems offers distinct advantages over liquid\u2010phase counterparts, including enhanced mass transfer, simplified product separation and reduced side reactions. Notably, near\u2010infrared (NIR) light constitutes approximately 50% of the solar spectrum; however, traditional photocatalysts rarely utilize this low\u2010energy region, thereby limiting overall solar\u2010to\u2010chemical conversion efficiency. This review systematically summarizes the rationale, design strategies and catalytic performance of NIR\u2010responsive photocatalysts for gas\u2010solid phase CO\n                    <jats:sub>2<\/jats:sub>\n                    RR. Key approaches include the engineering of metallic\/narrow\u2010bandgap conductors, the introduction of defects\/intermediate bands, the construction of plasmonic heterojunctions, atomic\u2010level doping, the integration of single\u2010atom active sites and the development of metal\u2010free photothermal systems. These strategies address core challenges such as extending spectral response, enhancing charge separation and optimizing CO\n                    <jats:sub>2<\/jats:sub>\n                    activation. Representative catalysts exhibit efficient NIR\u2010driven CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction to value\u2010added products (e.g., carbon monoxide, methane, methanol) with high selectivity and stability. This review provides critical insights into unlocking full\u2010spectrum solar energy utilization and advancing practical CO\n                    <jats:sub>2<\/jats:sub>\n                    RR technologies for carbon neutrality.\n                  <\/jats:p>","DOI":"10.1002\/chem.70997","type":"journal-article","created":{"date-parts":[[2026,4,16]],"date-time":"2026-04-16T07:33:25Z","timestamp":1776324805000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Near\u2010Infrared\u2010Responsive Catalysts for Gas\u2010Solid Phase Photocatalytic CO\n                    <sub>2<\/sub>\n                    Reduction: Design Strategies, Performance, Future Perspectives"],"prefix":"10.1002","volume":"32","author":[{"given":"Zihao","family":"Wang","sequence":"first","affiliation":[{"name":"Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education Faculty of Chemistry Northeast Normal 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