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The molar ratio of MeOH to the other alcohol and structure of the latter alcohol governed the distribution of three organic carbonates, that is, asymmetric alkyl methyl carbonate, dimethyl carbonate (DMC), and dialkyl carbonate. For primary alcohols such as ethanol, 1\u2010propanol, and 1\u2010butanol, an equimolar ratio of MeOH to the other alcohol afforded the highest distribution of the asymmetric alkyl methyl carbonate. In contrast, the low reactivity of 2\u2010propanol due to steric hindrance from its bulky alkyl moiety enabled the preferential formation of isopropyl methyl carbonate (iPMC) with &gt;80% distribution among the three carbonates of iPMC, DMC, and diisopropyl carbonate. The time\u2010course study indicated the involvement of two reaction routes for synthesizing asymmetric organic carbonates: (i) direct cross\u2010carboxylation of MeOH, the other alcohol, and CO\n                    <jats:sub>2<\/jats:sub>\n                    and (ii) transesterification between DMC, which is formed via homo\u2010carboxylation of MeOH and CO\n                    <jats:sub>2<\/jats:sub>\n                    , and the other alcohol. In the case of iPMC synthesis, the indirect route (ii) became dominant because of the low reactivity of 2\u2010propanol.\n                  <\/jats:p>","DOI":"10.1002\/chem.71064","type":"journal-article","created":{"date-parts":[[2026,5,1]],"date-time":"2026-05-01T16:00:32Z","timestamp":1777651232000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Cross\u2010Carboxylation of Methanol and Other Alcohols With CO\n                    <sub>2<\/sub>\n                    Into Asymmetric Alkyl Methyl Carbonates Over a CeO\n                    <sub>2<\/sub>\n                    Catalyst"],"prefix":"10.1002","volume":"32","author":[{"given":"Yuan","family":"Li","sequence":"first","affiliation":[{"name":"Department of Applied Chemistry Graduate School of Engineering Tohoku University  Sendai Miyagi Japan"},{"name":"Faculty of Environmental Science and Engineering Kunming University of Science and Technology  Kunming Yunnan 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