{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,4]],"date-time":"2026-09-04T08:12:03Z","timestamp":1788509523436,"version":"build-2803163510"},"reference-count":61,"publisher":"Wiley","issue":"31","license":[{"start":{"date-parts":[[2026,5,6]],"date-time":"2026-05-06T00:00:00Z","timestamp":1778025600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,5,6]],"date-time":"2026-05-06T00:00:00Z","timestamp":1778025600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2021YFA1501600"],"award-info":[{"award-number":["2021YFA1501600"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["92356308"],"award-info":[{"award-number":["92356308"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22371285"],"award-info":[{"award-number":["22371285"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2026,8,18]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Herein, we report a strategy employing chiral macrocycles for the in situ trapping of catalytically active anions, enabling highly efficient and enantioselective catalysis. By exploiting the strong anion\u2010binding ability of tailored bis\u2010thiourea macrocycles, active peroxotungstate species generated from a Na\n                    <jats:sub>2<\/jats:sub>\n                    WO\n                    <jats:sub>4<\/jats:sub>\n                    \/Na\n                    <jats:sub>3<\/jats:sub>\n                    PO\n                    <jats:sub>4<\/jats:sub>\n                    \/H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    system are selectively captured within a confined chiral cavity. Using only 1\u00a0mol% macrocycle, sulfide oxidation proceeds efficiently to afford sulfoxides in up to 95% yield and 91%\u00a0ee. Mechanistic studies identify a macrocycle\u2010bound phosphato\u2010bis(oxoperoxotungstate) complex as the key catalytic species. The pronounced macrocyclic effect and the fine stereochemical modulation in response to subtle structural variations underscore the precise control conferred by the confined environment. This work demonstrates that macrocyclic anion trapping can steer the reactivity and stereoselectivity of otherwise elusive polyanionic catalysts\u2014offering a distinct approach that operates beyond conventional cationic ion\u2010pairing systems. The strategy is expected to be applicable to a wide range of catalytic transformations involving active anionic species.\n                  <\/jats:p>","DOI":"10.1002\/chem.71092","type":"journal-article","created":{"date-parts":[[2026,5,6]],"date-time":"2026-05-06T07:48:52Z","timestamp":1778053732000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Chiral Macrocycle\u2010Enabled In\u2010Situ Trapping of Catalytically Active Peroxometalate Anions for Directing Asymmetric Sulfoxidation"],"prefix":"10.1002","volume":"32","author":[{"given":"Yun\u2010Long","family":"Bai","sequence":"first","affiliation":[{"name":"Beijing National Laboratory For Molecular Sciences CAS Key Laboratory of Molecular Recognition and Function Institute of Chemistry Chinese Academy of Sciences  Beijing China"},{"name":"University of Chinese Academy of Sciences  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rui","family":"Ning","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory For Molecular Sciences CAS Key Laboratory of Molecular Recognition and Function Institute of Chemistry Chinese Academy of Sciences  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xu\u2010Dong","family":"Wang","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory For Molecular Sciences CAS Key Laboratory of Molecular Recognition and Function Institute of Chemistry Chinese Academy of Sciences  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Li\u2010Xia","family":"Wang","sequence":"additional","affiliation":[{"name":"Huairou Research Center Institute of Chemistry Chinese Academy of Sciences  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jie","family":"Cui","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory For Molecular Sciences Center For Physicochemical Analysis and Measurement Institute of Chemistry Chinese Academy of Sciences  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jun\u2010Feng","family":"Xiang","sequence":"additional","affiliation":[{"name":"University of Chinese Academy of Sciences  Beijing China"},{"name":"Beijing National Laboratory For Molecular Sciences Center For Physicochemical Analysis and Measurement Institute of Chemistry Chinese Academy of Sciences  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9415-2181","authenticated-orcid":false,"given":"Yu\u2010Fei","family":"Ao","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory For Molecular Sciences CAS Key Laboratory of Molecular Recognition and Function Institute of Chemistry Chinese Academy of Sciences  Beijing China"},{"name":"University of Chinese Academy of Sciences  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9059-5022","authenticated-orcid":false,"given":"De\u2010Xian","family":"Wang","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory For Molecular Sciences CAS Key Laboratory of Molecular Recognition and Function Institute of Chemistry Chinese Academy of Sciences  Beijing China"},{"name":"University of Chinese Academy of Sciences  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5988-1293","authenticated-orcid":false,"given":"Qi\u2010Qiang","family":"Wang","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory For Molecular Sciences CAS Key Laboratory of Molecular Recognition and Function Institute of Chemistry Chinese Academy of Sciences  Beijing China"},{"name":"University of Chinese Academy of Sciences  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,5,6]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3CS60037H"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/cplu.202000152"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.4c00583"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5CS00835B"},{"key":"e_1_2_7_6_1","volume-title":"Phase\u2010Transfer Catalysis: Principles and Techniques","author":"Starks C. M.","year":"1978"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/9781788010917"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201206835"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201601441"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201800326"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202003673"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1405"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201205449"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr960400y"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr960401q"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr960403a"},{"key":"e_1_2_7_17_1","volume-title":"Catalysts for Fine Chemical Synthesis: Catalysis by Polyoxometalates","author":"Kozhevnikov I. V.","year":"2002"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr500390v"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/b303160h"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr00027a002"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2004.11.019"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molcata.2006.01.027"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/asia.202100686"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS00392A"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CY00674K"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200800759"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200901512"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2jm16398e"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2016.05.019"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201601574"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms13455"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b04862"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5c03530"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202403856"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202401940"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11426\u2010024\u20102168\u20104"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202507981"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo00123a046"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.carres.2012.03.034"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b07525"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4SC01949K"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.5c01892"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr990372u"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr900147h"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CS00703A"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo00169a052"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1016\/0304\u20105102(85)85037\u20109"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo00250a032"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00107a012"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1381\u20101169(96)00257\u20109"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0040\u20104020(01)00068\u20100"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic00083a008"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1021\/ol047996t"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.0c00732"},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo900385d"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201702926"},{"key":"e_1_2_7_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202314790"},{"key":"e_1_2_7_58_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7MD00573C"},{"key":"e_1_2_7_59_1","unstructured":"M. J.Frisch et\u00a0al. \u201cGaussian 16 Revision A.03 \u201d (Gaussian Inc. 2016)."},{"key":"e_1_2_7_60_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.464913"},{"key":"e_1_2_7_61_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.37.785"},{"key":"e_1_2_7_62_1","doi-asserted-by":"publisher","DOI":"10.1039\/b508541a"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.71092","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.71092","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.71092","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,18]],"date-time":"2026-08-18T18:48:54Z","timestamp":1787078934000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.71092"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,5,6]]},"references-count":61,"journal-issue":{"issue":"31","published-print":{"date-parts":[[2026,8,18]]}},"alternative-id":["10.1002\/chem.71092"],"URL":"https:\/\/doi.org\/10.1002\/chem.71092","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,5,6]]},"assertion":[{"value":"2026-02-26","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-04-21","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-05-06","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e71092"}}