{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,25]],"date-time":"2026-08-25T15:32:31Z","timestamp":1787671951263,"version":"build-2736575974"},"reference-count":47,"publisher":"Wiley","issue":"32","license":[{"start":{"date-parts":[[2026,5,9]],"date-time":"2026-05-09T00:00:00Z","timestamp":1778284800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,5,9]],"date-time":"2026-05-09T00:00:00Z","timestamp":1778284800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100007684","name":"Ministry of Education and Science of Ukraine","doi-asserted-by":"publisher","award":["25BF037\u201001(0125U002249)"],"award-info":[{"award-number":["25BF037\u201001(0125U002249)"]}],"id":[{"id":"10.13039\/501100007684","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2026,8,24]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Alkenyl fluorosulfates are evaluated as the partners of palladium\u2010catalyzed cross\u2010coupling reactions and an alternative to more common triflates and halides. Efficient protocols for the multigram synthesis of title reactants using the reaction of carbonyl compounds with SO\n                    <jats:sub>2<\/jats:sub>\n                    F\n                    <jats:sub>2<\/jats:sub>\n                    were documented. Reactivity of alkenyl fluorosulfates in Suzuki, Sonogashira, Heck, Stille, and Buchwald\u2010Hartwig reactions, as well as Miyaura borylation under typical conditions, was studied, and limitations of the methods were established. It was found that alkenyl flurosulfates have similar or even higher reactivity in the cross\u2010coupling reactions as compared to alkenyl triflates.\n                  <\/jats:p>","DOI":"10.1002\/chem.71098","type":"journal-article","created":{"date-parts":[[2026,5,9]],"date-time":"2026-05-09T12:05:37Z","timestamp":1778328337000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Alkenyl Fluorosulfates\u2014Expedient Partners for Palladium\u2010Catalyzed Cross\u2010Coupling Reactions"],"prefix":"10.1002","volume":"32","author":[{"given":"Vladyslav","family":"Hnativ","sequence":"first","affiliation":[{"name":"Enamine Ltd.  Ky\u0457v Ukraine"},{"name":"Taras Shevchenko National University of Kyiv  Ky\u0457v Ukraine"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Serhii","family":"Aleksandrenko","sequence":"additional","affiliation":[{"name":"Enamine Ltd.  Ky\u0457v Ukraine"},{"name":"Taras Shevchenko National University of Kyiv  Ky\u0457v Ukraine"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Serhii","family":"Zhersh","sequence":"additional","affiliation":[{"name":"Enamine Ltd.  Ky\u0457v Ukraine"},{"name":"Taras Shevchenko National University of Kyiv  Ky\u0457v Ukraine"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6036-5859","authenticated-orcid":false,"given":"Oleksandr O.","family":"Grygorenko","sequence":"additional","affiliation":[{"name":"Enamine Ltd.  Ky\u0457v Ukraine"},{"name":"Taras Shevchenko National University of Kyiv  Ky\u0457v Ukraine"},{"name":"Enamine Scientific Research Institute  Ky\u0457v Ukraine"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,5,9]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201107017"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202102108"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.bbi.2008.05.010"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CC04893K"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2008.11.010"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/NCHEM.1652;SUBJMETA"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/ACS.CHEMREV.6B00512"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/ANIE.201904795"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/ACS.ORGANOMET.8B00720"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/ACSCATAL.0C04520\/SUPPL_FILE\/CS0C04520_SI_004.CIF"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0040\u20104039(00)60957\u20107"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/J.ECOENV.2023.115663"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/JO00011A010"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/ADSC.202301024"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3RA01791E"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/CHEM.201600167"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0040\u20104039(00)60311\u20108"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/J.CCLET.2024.110206"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/ADSC.202400401"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/ACS.ORGLETT.1C01907"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/CHEM.202301420"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1029\/2008JD011162"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aat5440"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19821150238"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0040\u20104020(01)86672\u20102"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/JO00060A041"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1246\/BCSJ.20200160"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/JO00213A021"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/J.BMC.2009.04.013"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/JA301326K"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1246\/CL.2000.126"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/JA0202255"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c06177"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/B978-075067571-0\/50007-7"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/JM030505A"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/ACS.ORGLETT.2C01015"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/ML300143D"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/JA903946F"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202421258"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202001394"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201404398"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201204427"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/EJOC.201801445"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/ACS.ORGLETT.5C00015"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/OL050794S"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/EJOC.200700367"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1021\/JM061043E"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.71098","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.71098","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.71098","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,25]],"date-time":"2026-08-25T15:11:43Z","timestamp":1787670703000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.71098"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,5,9]]},"references-count":47,"journal-issue":{"issue":"32","published-print":{"date-parts":[[2026,8,24]]}},"alternative-id":["10.1002\/chem.71098"],"URL":"https:\/\/doi.org\/10.1002\/chem.71098","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,5,9]]},"assertion":[{"value":"2026-01-16","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-04-21","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-05-09","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e71098"}}