{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,18]],"date-time":"2026-08-18T19:26:24Z","timestamp":1787081184474,"version":"build-2736575974"},"reference-count":37,"publisher":"Wiley","issue":"31","license":[{"start":{"date-parts":[[2026,5,11]],"date-time":"2026-05-11T00:00:00Z","timestamp":1778457600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,5,11]],"date-time":"2026-05-11T00:00:00Z","timestamp":1778457600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["438795198"],"award-info":[{"award-number":["438795198"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2026,8,18]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Black, needle\u2010shaped crystals of K\n                    <jats:sub>6<\/jats:sub>\n                    [Sb\n                    <jats:sub>12<\/jats:sub>\n                    O\n                    <jats:sub>18<\/jats:sub>\n                    ](SbOTe\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    \u00b7\n                    <jats:italic>n<\/jats:italic>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    O (\n                    <jats:italic>n<\/jats:italic>\n                    \u2248 5) were grown in high yield from an alkaline medium under hydrothermal conditions. Microporous, single\u2010walled [Sb\n                    <jats:sub>12<\/jats:sub>\n                    O\n                    <jats:sub>18<\/jats:sub>\n                    ] nanotubes dominate the hexagonal crystal structure of the cetineite\u2010type. Antimony(III) atoms form the outer and oxygen atoms the inner wall of the nanotube, making it radially dipolar, similar to a cylindrical capacitor. The inner wall is decorated with potassium cations, and water molecules fill the remaining internal volume of the nanotube. Stacks of the hitherto unknown oxidotritelluridoantimonate(V) anion, (SbOTe\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sup>3\u2212<\/jats:sup>\n                    , fill the trigonal channels in the packing of the nanotubes. As with other modifications of Sb\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    , the filled bonding and empty antibonding states of the nanotubes are separated by a wide band gap of about 3.6 eV. In this energy gap, the molecular orbitals of the (SbOTe\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sup>3\u2212<\/jats:sup>\n                    anions are located. Electronic excitation involves a charge transfer from the anions to the nanotubes, which are thereby heavily n\u2010doped and exhibit semiconducting behavior. Modification of the reaction conditions results in the crystallization of the tellurium\u2010rich cetineite K\n                    <jats:sub>6<\/jats:sub>\n                    [Sb\n                    <jats:sub>12<\/jats:sub>\n                    O\n                    <jats:sub>18<\/jats:sub>\n                    ](Te\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    (Te\n                    <jats:sub>2<\/jats:sub>\n                    )\n                    <jats:sub>3<\/jats:sub>\n                    \u00b75H\n                    <jats:sub>2<\/jats:sub>\n                    O or the cetineite K\n                    <jats:sub>18<\/jats:sub>\n                    [Sb\n                    <jats:sub>36<\/jats:sub>\n                    O\n                    <jats:sub>54<\/jats:sub>\n                    ](SbOTe\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    (Te\n                    <jats:sub>2<\/jats:sub>\n                    )\n                    <jats:sub>6<\/jats:sub>\n                    \u00b722H\n                    <jats:sub>2<\/jats:sub>\n                    O, which contains [Sb\n                    <jats:sub>36<\/jats:sub>\n                    O\n                    <jats:sub>54<\/jats:sub>\n                    ] nanotubes with an even wider diameter.\n                  <\/jats:p>","DOI":"10.1002\/chem.71106","type":"journal-article","created":{"date-parts":[[2026,5,12]],"date-time":"2026-05-12T04:20:22Z","timestamp":1778559622000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Semiconducting Single\u2010Wall Antimony Oxide Nanotubes and Oxidotritelluridoantimonate(V) Anions"],"prefix":"10.1002","volume":"32","author":[{"given":"Huanyu","family":"He","sequence":"first","affiliation":[{"name":"Faculty of Chemistry and Food Chemistry TUD Dresden University of Technology  Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Oleg","family":"Janson","sequence":"additional","affiliation":[{"name":"Leibniz Institute for Solid State and Materials Research Dresden  Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6392-1355","authenticated-orcid":false,"given":"Vitaliy","family":"Romaka","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry and Food Chemistry TUD Dresden University of Technology  Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2391-6025","authenticated-orcid":false,"given":"Michael","family":"Ruck","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry and Food Chemistry TUD Dresden University of Technology  Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,5,11]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1146\/annurev.matsci.34.040203.112300"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.trac.2022.116741"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.2c00140"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0992\u20104361(98)80012\u2010X"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1524\/zkri.1999.214.12.820"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19971091018"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200351284"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200603075"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/b312550e"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0567740874002986"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.5560\/znb.2012-0117"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1524\/zkri.2012.1478"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1006\/jssc.1994.1374"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1524\/zkri.1991.197.3-4.255"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022-4596(91)90202-S"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0108768190011041"},{"key":"e_1_2_7_18_1","volume-title":"Thermochemical 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