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Creating hybrid systems between those materials allows us to combine the best of both worlds, and by tailored chemical modification, these heterostructure assemblies can be engineered and fine\u2010tuned toward desired applications. This study systematically investigates laser\u2010induced covalent functionalization of BP nanosheets and graphene\u2010BP (G\u2010BP) van der Waals (vdW) heterostructures using dibenzoyl peroxide\u2010based precursors. Although pristine BP exhibits extreme sensitivity to laser irradiation, the formation of the G\u2010BP heterostructure successfully enabled detailed Raman spectroscopy investigations and the successful spatially\u2010resolved covalent functionalization of the graphene layer under mild laser conditions. Moreover, the G\u2010BP hybrids revealed thickness\u2010dependent intensity modulation of the graphene Raman bands due to interference effects, which was successfully modelled and exploited for the heterostructure characterization. The reversibility of the functional group attachment was investigated via temperature\u2010dependent (T\u2010dependent) Raman studies.<\/jats:p>","DOI":"10.1002\/chem.71127","type":"journal-article","created":{"date-parts":[[2026,5,14]],"date-time":"2026-05-14T12:09:33Z","timestamp":1778760573000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Laser\u2010Induced Chemical Patterning of Graphene\u2010Black Phosphorus Hybrids"],"prefix":"10.1002","volume":"32","author":[{"given":"Jasmin","family":"Eisenkolb","sequence":"first","affiliation":[{"name":"Department of Chemistry and Pharmacy &amp; Center of Advanced Materials and Processes (ZMP) Friedrich\u2010Alexander Universit\u00e4t Erlangen\u2010N\u00fcrnberg  F\u00fcrth Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mhamed","family":"Assebban","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Pharmacy &amp; Center 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