{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,18]],"date-time":"2026-09-18T13:05:56Z","timestamp":1789736756814,"version":"4.0.1"},"reference-count":66,"publisher":"Wiley","issue":"35","license":[{"start":{"date-parts":[[2026,6,1]],"date-time":"2026-06-01T00:00:00Z","timestamp":1780272000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,6,1]],"date-time":"2026-06-01T00:00:00Z","timestamp":1780272000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2026,9,19]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Structural phase transitions of metal\u2013organic frameworks (MOFs) induced by guest\u2010molecule exchange within their pores have attracted considerable attention not only from the viewpoint of structural chemistry but also for the modulation of their functional properties. Herein, we report a reversible structural phase transition triggered by the exchange of coordinative guest molecules in a Pb\u2010based MOF composed of Pb\n                    <jats:sup>2+<\/jats:sup>\n                    ions and 2,5\u2010dihydroxy\u20101,4\u2010benzoquinone (H\n                    <jats:sub>2<\/jats:sub>\n                    DHBQ), formulated as [Pb(DHBQ)(DMF)(H\n                    <jats:sub>2<\/jats:sub>\n                    O)] (DMF\u00a0=\n                    <jats:italic>N<\/jats:italic>\n                    ,\n                    <jats:italic>N<\/jats:italic>\n                    \u2010dimethylformamide). This compound forms a 3D framework structure in which 1D Pb\u2013O rods, constructed from Pb\n                    <jats:sup>2+<\/jats:sup>\n                    ions and oxygen atoms of bridging DHBQ\n                    <jats:sup>2\u2212<\/jats:sup>\n                    ligands, serve as secondary building units (SBUs). The framework contains 1D pores accommodating coordinative DMF and H\n                    <jats:sub>2<\/jats:sub>\n                    O molecules. Exchange of these guest molecules induces a reversible structural phase transition accompanied by significant changes in both the Pb\u2013O rod structure and the overall dimensionality of the framework. To the best of our knowledge, this represents the first example of a MOF composed of rigid SBUs that exhibits a reversible structural phase transition involving a change in framework dimensionality driven by guest\u2010molecule exchange. These findings provide new insight into dynamic structural transformations in MOFs and highlight a strategy for controlling framework topology and properties through guest coordination.\n                  <\/jats:p>","DOI":"10.1002\/chem.71203","type":"journal-article","created":{"date-parts":[[2026,6,2]],"date-time":"2026-06-02T02:04:48Z","timestamp":1780365888000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Coordinative\u2010Guest\u2010Triggered Dimensional Crossover in a Metal\u2013Organic Framework With Rigid Metal\u2013Oxo Rods"],"prefix":"10.1002","volume":"32","author":[{"given":"Keisuke","family":"Ishikawa","sequence":"first","affiliation":[{"name":"Department of Chemistry Faculty of Science Tokyo University of Science  Tokyo Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4688-2822","authenticated-orcid":false,"given":"Kazuya","family":"Otsubo","sequence":"additional","affiliation":[{"name":"Department of Chemistry Faculty of Science Tokyo University of Science  Tokyo Japan"},{"name":"Research Institute for Science and Technology Division of Joint Research of Geometry and Natural Science Tokyo University of Science  Chiba Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,6,1]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1230444"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200300610"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/B802426J"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr200190s"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/B802256A"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00223"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00093E"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00766"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202106259"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2SC04314A"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr200256v"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar000034b"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00346"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521\u20103773(19990903)38:17<2590::AID\u2010ANIE2590>3.0.CO;2\u2010H"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.681"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja053992n"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/1521\u20103773(20020118)41:2<281::AID\u2010ANIE281>3.0.CO;2\u2010Y"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar400265x"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00101J"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja055757a"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja031836f"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200604284"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1039\/B312589K"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic801624v"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja906041f"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic0611948"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic8020518"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/C2JM30389B"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic4020256"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201204806"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/cg300617h"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1039\/C2CC37497H"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1387\u20101811(99)00120\u20101"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.5b01711"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja045123o"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja0276974"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja802589u"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200703086"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200462100"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201912195"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1039\/C0DT00085J"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja711040s"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.5b01963"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1039\/B800126J"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic100753g"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.7b00592"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja902101x"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1039\/C1CC12184G"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202117417"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3CC03540A"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.6b02840"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja804936z"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.2c13500"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202010549"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201001398"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1021\/cg900276g"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.6b00617"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja01160a122"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1107\/S2053273314026370"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1107\/S2053229614024218"},{"key":"e_1_2_8_62_1","unstructured":"CrystalStructure 4.3: Crystal Structure Analysis Package Rigaku Corporation 2000\u20132019."},{"key":"e_1_2_8_63_1","volume-title":"Gaussian 09","author":"Frisch M. J.","year":"2013"},{"key":"e_1_2_8_64_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.478522"},{"key":"e_1_2_8_65_1","doi-asserted-by":"publisher","DOI":"10.1016\/0009\u20102614(82)80012\u20102"},{"key":"e_1_2_8_66_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.448975"},{"key":"e_1_2_8_67_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.455064"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.71203","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.71203","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.71203","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,18]],"date-time":"2026-09-18T12:26:25Z","timestamp":1789734385000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.71203"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,6,1]]},"references-count":66,"journal-issue":{"issue":"35","published-print":{"date-parts":[[2026,9,19]]}},"alternative-id":["10.1002\/chem.71203"],"URL":"https:\/\/doi.org\/10.1002\/chem.71203","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,6,1]]},"assertion":[{"value":"2026-03-20","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-05-18","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-06-01","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e71203"}}