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The discussion is systematically organized around the multifaceted roles of nitroarenes in excited\u2010state transformations, including their applications as hydrogen atom transfer (HAT) and oxygen atom transfer (OAT) reagents to enable the functionalization of inert C\u2500H bonds and the oxidative cleavage of alkenes and arenes. Their utility as nitrene precursors for the construction of complex heterocycles is also summarized. Furthermore, nitroarenes can act as energy transfer (EnT) catalysts and proton\u2010coupled electron transfer (PCET) reagents, and the nitro group serves as a leaving group under light irradiation. Relying on the distinct electronic configurations of singlet and triplet excited states, these strategies allow diverse transformations such as cross\u2010couplings, cyclization reactions, and skeletal editing to proceed under mild and sustainable conditions. This emerging field not only enriches the synthetic toolkit for the assembly of valuable molecular frameworks but also provides new avenues for the late\u2010stage modification of pharmaceuticals and fine chemicals.<\/jats:p>","DOI":"10.1002\/chem.71274","type":"journal-article","created":{"date-parts":[[2026,6,18]],"date-time":"2026-06-18T15:51:36Z","timestamp":1781797896000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Light Induced Transformations of the NO\n                    <sub>2<\/sub>\n                    Group in Nitroarenes"],"prefix":"10.1002","volume":"32","author":[{"given":"Tiantian","family":"Liang","sequence":"first","affiliation":[{"name":"Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction Ministry of Education College of Chemistry Central China Normal University (CCNU)  Wuhan P. R. 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