{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,7]],"date-time":"2026-07-07T13:19:27Z","timestamp":1783430367368,"version":"3.54.6"},"reference-count":51,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,7,7]],"date-time":"2026-07-07T00:00:00Z","timestamp":1783382400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,7,7]],"date-time":"2026-07-07T00:00:00Z","timestamp":1783382400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The combination of bispidine ligand\n                    <jats:bold>L1<\/jats:bold>\n                    and Mn(II) produces CP 1\u2010MeCN with a one\u2010dimensional (1D) architecture unprecedented for bispidine\u2010based CPs. Single\u2010crystal X\u2010ray diffraction (SC\u2010XRD) reveals a robust framework of orthogonally oriented ribbon\u2010like chains in the tetragonal space group\n                    <jats:italic>P<\/jats:italic>\n                    4\n                    <jats:sub>2<\/jats:sub>\n                    2\n                    <jats:sub>1<\/jats:sub>\n                    2 with solvent\u2010filled perpendicularly intersecting channels that account for about 30% of the unit\u2010cell volume. Volatile organic compound (VOC) exchange on SC proceeds via clean SC\u2010to\u2010SC transformations with nitrobenzene (NB), chlorobenzene (ClBz), and 1,2\u2010dichlorobenzene (DCB), but not with toluene (Tol). The corresponding microcrystalline powder,\n                    <jats:bold>\n                      1\u2010MeCN\n                      <jats:sup>Pwd<\/jats:sup>\n                    <\/jats:bold>\n                    , and its thermally generated evacuated amorphous phase,\n                    <jats:bold>\n                      1\u2010amorph\n                      <jats:sup>Pwd<\/jats:sup>\n                    <\/jats:bold>\n                    , were tested as well. In particular,\n                    <jats:bold>\n                      1\u2010amorph\n                      <jats:sup>Pwd<\/jats:sup>\n                    <\/jats:bold>\n                    adsorbs ca. 1.6\u20131.9\u00a0mmol\/g of aromatic NB, ClBz, and DCB (but only 0.7 for Tol) and up to 2.5\u00a0mmol\/g of MeCN, under saturated vapor conditions at r.t. Although these uptake capacities are comparable to those of previously reported bispidine\u2010based CP sorbents, the preservation of the orthogonal chain packing motif upon guest uptake and the distinct interaction mechanism with the tested VOCs highlight a different role of chain topology and packing in governing sorption and offer new design criteria for the development of novel VOC\u2010capturing materials.\n                  <\/jats:p>","DOI":"10.1002\/chem.71316","type":"journal-article","created":{"date-parts":[[2026,7,7]],"date-time":"2026-07-07T13:02:23Z","timestamp":1783429343000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["VOCs Adsorption and Exchange Properties in Bispidine\u2010Based Mn(II) 1D CPs Made of Orthogonally Oriented Linear Chains"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3401-4294","authenticated-orcid":false,"given":"Meriem","family":"Goudjil","sequence":"first","affiliation":[{"name":"Department of Industrial Engineering University of Firenze  Firenze Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2861-332X","authenticated-orcid":false,"given":"Martina","family":"Lippi","sequence":"additional","affiliation":[{"name":"Department of Industrial Engineering University of Firenze  Firenze Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0001-8093-7084","authenticated-orcid":false,"given":"Sara","family":"Camorali","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Materials and Chemical Engineering \u201cGiulio Natta\u201d Politecnico di Milano  Milano 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