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This approach enables direct coupling with various aminoquinones under mild conditions. Mechanistic investigations support an ionic photo\u2010S\n                    <jats:sub>N<\/jats:sub>\n                    1 pathway over a radical manifold, with evidence suggesting that energy transfer from the excited state of the aminoquinone to the diazonium salt facilitates the formation of triplet phenyl cations, which serve as the reactive intermediates in the arylation process.\n                  <\/jats:p>","DOI":"10.1002\/chem.71331","type":"journal-article","created":{"date-parts":[[2026,6,24]],"date-time":"2026-06-24T04:06:31Z","timestamp":1782273991000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["External Photocatalyst\u2010Free C\u2500H Arylation of Aminoquinones Through a Photo\u2010S\n                    <sub>N<\/sub>\n                    1 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