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Specifically, we compare the behavior of structurally related dyes obtained by peripheral substitution of a prototypical thermally activated delayed fluorescence (TADF) dye, DMAC\u2010TRZ. Decorating the donor (DMAC) moiety with two phenyl groups, a blue\u2010shift of the emission is obtained, as sought, and an increase of the spin\u2013orbit coupling, suggesting amplified TADF. Quite surprisingly, subtle geometrical rearrangements of the two peripheral groups upon photoexcitation suppress again spin\u2013orbit coupling, leading overall to a similar photophysics as DMAC\u2010TRZ.<\/jats:p>","DOI":"10.1002\/chem.71352","type":"journal-article","created":{"date-parts":[[2026,7,12]],"date-time":"2026-07-12T14:50:06Z","timestamp":1783867806000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Thermally Activated Delayed Fluorescence: An Extended Study of Peripherally Substituted DMAC\u2010TRZ Analogues"],"prefix":"10.1002","author":[{"given":"Andrea","family":"Landi","sequence":"first","affiliation":[{"name":"Department of Chemistry, Life Science and Environmental Sustainability, Parco Area delle Scienze 17\/a University of Parma Parma Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ottavia","family":"Racchi","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Life Science and Environmental Sustainability, Parco Area delle Scienze 17\/a University of Parma Parma Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4542-6190","authenticated-orcid":false,"given":"D. 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