{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,8]],"date-time":"2026-07-08T13:17:06Z","timestamp":1783516626245,"version":"3.55.0"},"reference-count":49,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,7,8]],"date-time":"2026-07-08T00:00:00Z","timestamp":1783468800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,7,8]],"date-time":"2026-07-08T00:00:00Z","timestamp":1783468800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Heterogeneous catalysis achieves efficient thermal decomposition of ammonium perchlorate (AP) by creating abundant catalytically active sites and optimizing mass transfer and diffusion processes. Based on this, hollow nickel\u2013cobalt\u2010layered double hydroxide (H\u2010NiCo\u2010LDH) nanocages derived from metal\u2013organic frameworks (MOFs) were successfully synthesized using an etching\u2010deposition\u2010growth strategy. The hollow structure and surface mesopores of H\u2010NiCo\u2010LDH not only expose more abundant catalytically active sites but also enhance the mass transfer and diffusion efficiency of gas\u2010phase intermediate products. The bimetallic synergy between Ni and Co effectively modulates the electronic structure, facilitating electron transfer during the catalytic reaction and promoting the deep oxidation of NH\n                    <jats:sub>3<\/jats:sub>\n                    to higher\u2010valence nitrogen oxides. Performance tests demonstrate that adding 5% H\u2010NiCo\u2010LDH significantly advances the high\u2010temperature thermal decomposition temperature of AP by 109.7\u00b0C and markedly increases the content of higher\u2010valence nitrogen oxides in the decomposition products. Furthermore, incorporating H\u2010NiCo\u2010LDH shortens the overall combustion time of AP while enhancing the flame brightness. This work not only demonstrates exceptional performance of H\u2010NiCo\u2010LDH in catalyzing AP thermal decomposition but also provides novel insights for developing efficient AP thermal decomposition catalysts through structural design and composition regulation.\n                  <\/jats:p>","DOI":"10.1002\/chem.71370","type":"journal-article","created":{"date-parts":[[2026,7,8]],"date-time":"2026-07-08T12:38:17Z","timestamp":1783514297000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Hollow NiCo\u2010LDH Nanocage Derived From ZIF\u201067 as an Efficient Catalyst for the Thermal Decomposition of Ammonium Perchlorate"],"prefix":"10.1002","author":[{"given":"Weihang","family":"Cheng","sequence":"first","affiliation":[{"name":"College of Chemistry and Molecular Sciences Wuhan University  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qihui","family":"Zeng","sequence":"additional","affiliation":[{"name":"National Key Laboratory of Aerospace Chemical Power Hubei Institute of Aerospace Chemotechnology  Xiangyang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaolin","family":"Tang","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Sciences Wuhan University  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuming","family":"Zhou","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Sciences Wuhan University  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junyu","family":"Li","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Sciences Wuhan University  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yixin","family":"Liu","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Sciences Wuhan University  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2546-9502","authenticated-orcid":false,"given":"Yifu","family":"Zhang","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Sciences Wuhan University  Wuhan China"},{"name":"Hubei Key Laboratory of Radiation Chemistry and Functional Materials School of Nuclear Technology and Chemistry &amp; Biology Hubei University of Science and Technology  Xianning China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0009-7903-2171","authenticated-orcid":false,"given":"Haiyan","family":"Liu","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Sciences Wuhan University  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0265-2438","authenticated-orcid":false,"given":"Chi","family":"Huang","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Sciences Wuhan University  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,7,8]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202501163"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2025.163537"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ceramint.2025.07.141"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2022.167134"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jiec.2024.01.062"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3TA00878A"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2024.159872"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0QI01337D"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2024.133122"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.surfin.2024.104639"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtchem.2023.101640"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2022.164624"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2024.136961"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202309302"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.dt.2022.06.012"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2020.154837"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2024.177486"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2020.122015"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2016.03.071"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202300321"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijhydene.2022.03.256"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2020.124458"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.vacuum.2018.10.020"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ces.2025.121870"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202303025"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.134730"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.3c15403"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apmt.2025.102640"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2022.214666"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2025.132264"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.202100997"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.9b02106"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.8b02127"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2018.08.018"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12274\u2010022\u20104144\u20106"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jece.2023.111855"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2020.125216"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2015.01.041"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2019.123051"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2016.03.015"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.clay.2013.02.004"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2019.144598"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijhydene.2020.05.052"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.susmat.2025.e01413"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.2c08903"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tca.2005.11.038"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.surfin.2026.108740"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2026.165899"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.38.1881"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.71370","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.71370","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.71370","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,8]],"date-time":"2026-07-08T12:38:18Z","timestamp":1783514298000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.71370"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7,8]]},"references-count":49,"alternative-id":["10.1002\/chem.71370"],"URL":"https:\/\/doi.org\/10.1002\/chem.71370","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7,8]]},"assertion":[{"value":"2026-02-04","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-06-24","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-07-08","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e71370"}}