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Electrocatalytic C\u2500N coupling, driven by renewable electricity under mild conditions, offers a sustainable route for converting simple feedstocks into value\u2010added nitrogen\u2010containing compounds and thus provides a promising strategy for glycine production. Bismuth\u2010based catalysts are commonly used in the electrosynthesis of amino acids. Herein, we report a Bi\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>3<\/jats:sub>\n                    nanosheet\u2010based catalyst for glycine electrosynthesis under acidic conditions, achieving 67.5% Faradaic efficiency (FE) and a yield rate of 0.51\u00a0mmol h\n                    <jats:sup>\u22121<\/jats:sup>\n                    cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    at 200\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . Operando Raman and attenuated total reflectance surface\u2010enhanced infrared absorption spectroscopy (ATR\u2010SEIRAS) identify catalyst reconstruction and a tandem mechanism mediated by NH\n                    <jats:sub>2<\/jats:sub>\n                    OH and oxime intermediates. Combined with the control sulfurization experiment on Bi, we found that sulfur incorporation can modulate the product selectivity, possibly by influencing the subsequent hydrogenation of the oxime intermediate to glycine.\n                  <\/jats:p>","DOI":"10.1002\/chem.71380","type":"journal-article","created":{"date-parts":[[2026,7,7]],"date-time":"2026-07-07T13:04:17Z","timestamp":1783429457000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Electrosynthesis of Glycine From Nitrate and Glyoxylic Acid Over a Bi\n                    <sub>2<\/sub>\n                    S\n                    <sub>3<\/sub>\n                    Nanosheets\u2010Based Catalyst"],"prefix":"10.1002","author":[{"given":"Xulin","family":"Nong","sequence":"first","affiliation":[{"name":"Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering East China University of Science and Technology  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chunqi","family":"Yang","sequence":"additional","affiliation":[{"name":"Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering East China University of Science and Technology  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jingwen","family":"Zhuang","sequence":"additional","affiliation":[{"name":"Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering East China University of Science and Technology  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4086-0323","authenticated-orcid":false,"given":"Yuhang","family":"Li","sequence":"additional","affiliation":[{"name":"Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering East China University of Science and Technology  Shanghai China"},{"name":"Department of Chemical Engineering, School of Chemistry and Chemical Engineering Shanghai Jiao Tong University  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,7,7]]},"reference":[{"key":"e_1_2_7_2_1","first-page":"457","article-title":"Ribosome\u2010Mediated Polymerization of Long Chain Carbon and Cyclic Amino Acids Into Peptides in Vitro","volume":"11","author":"Lee J.","year":"2020","journal-title":"Nature 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