{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,12]],"date-time":"2026-07-12T15:05:35Z","timestamp":1783868735894,"version":"3.55.0"},"reference-count":80,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,7,12]],"date-time":"2026-07-12T00:00:00Z","timestamp":1783814400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,7,12]],"date-time":"2026-07-12T00:00:00Z","timestamp":1783814400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100008131","name":"Rheinische Friedrich-Wilhelms-Universit\u00e4t Bonn","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100008131","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    \u03c0\u2010Extended conjugation offers the opportunity to unveil new frontiers in materials, coupling redox activity with tunable photophysical properties. Here, we report a new family of \u03c0\u2010conjugated salen ligands bearing phenylene bridges and tunable substituents, together with their corresponding boron difluoride complexes. Owing to the extended \u03c0\u2010delocalization, these new compounds show promising results in electrochemical CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction to CO, achieving a remarkable Faradaic efficiency for an organocatalyst (up to 56%). Electrochemical, spectroscopic, and computational analyses support a ligand\u2010centered mechanism in which single\u2010electron reduction activates the framework for CO\n                    <jats:sub>2<\/jats:sub>\n                    binding at the imine nitrogen, forming an N\u2010bound CO\n                    <jats:sub>2<\/jats:sub>\n                    H intermediate. Beyond electrocatalysis, coordination to boron rigidifies the \u03c0\u2010framework, producing emissive boron\u2010salphen complexes with large Stokes shifts (&gt;7000 cm\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>1<\/jats:sup>\n                    ). These complexes function as efficient photosensitizers for singlet\u2010oxygen generation, enabling mild oxidative cleavage of alkenes under blue\u2010light irradiation. This work demonstrates that \u03c0\u2010extension transforms the traditional salphen framework into a redox\u2010active engine for small\u2010molecule activation, bypassing the need for transition metals in CO\n                    <jats:sub>2<\/jats:sub>\n                    electroreduction while simultaneously unlocking good photosensitizing capabilities.\n                  <\/jats:p>","DOI":"10.1002\/chem.71385","type":"journal-article","created":{"date-parts":[[2026,7,12]],"date-time":"2026-07-12T14:57:06Z","timestamp":1783868226000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["\u03c0\u2010Extended Salphen Scaffolds Enable CO\n                    <sub>2<\/sub>\n                    Electroreduction and Singlet Oxygen Generation"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-9068-3092","authenticated-orcid":false,"given":"Vincenzo","family":"Langellotti","sequence":"first","affiliation":[{"name":"Department of Chemical Sciences, University of Naples Federico II University Campus of Monte S. Angelo  Naples Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andr\u00e9","family":"Korzun","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Bonn  Bonn Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8636-5638","authenticated-orcid":false,"given":"Morgan J.","family":"McKee","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Bonn  Bonn Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5842-7600","authenticated-orcid":false,"given":"Massimo","family":"Melchiorre","sequence":"additional","affiliation":[{"name":"Department of Chemical Sciences, University of Naples Federico II University Campus of Monte S. Angelo  Naples Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7112-6186","authenticated-orcid":false,"given":"Taegeun","family":"Jo","sequence":"additional","affiliation":[{"name":"Department of Chemistry\u2013\u00c5ngstr\u00f6m Laboratory Uppsala University  Uppsala Sweden"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7902-3066","authenticated-orcid":false,"given":"J. Felipe","family":"Estrada\u2010Ruiz","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Bonn  Bonn Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6489-2106","authenticated-orcid":false,"given":"Gregor","family":"Schnakenburg","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Bonn  Bonn Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0279-4903","authenticated-orcid":false,"given":"Stefano","family":"Crespi","sequence":"additional","affiliation":[{"name":"Department of Chemistry\u2013\u00c5ngstr\u00f6m Laboratory Uppsala University  Uppsala Sweden"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1624-079X","authenticated-orcid":false,"given":"Francesco","family":"Ruffo","sequence":"additional","affiliation":[{"name":"Department of Chemical Sciences, University of Naples Federico II University Campus of Monte S. Angelo  Naples Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nikolay","family":"Kornienko","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Bonn  Bonn Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5840-1144","authenticated-orcid":false,"given":"Alessandro","family":"Bismuto","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Bonn  Bonn Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,7,12]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"crossref","first-page":"410","DOI":"10.1039\/B307853C","article-title":"Metal\u2013Salen Schiff Base Complexes in Catalysis: Practical Aspects","volume":"33","author":"Cozzi P. 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